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Alkanolamine · CAS 102-71-6

Triethanolamine (TEA)

C6H15NO3 Molar mass 149.19 g/mol

Triethanolamine is the tertiary ethanolamine in this part of our range, a well-documented cement grinding aid and cosmetic pH adjuster carrying an IARC Group 3 (not classifiable) finding -- categorically different from, and not to be confused with, its relative Diethanolamine's Group 2B status -- and no harmonised EU hazard classification, which we state honestly rather than imply a precision the data doesn't have.

Identification Sheet REP.
IUPAC name2,2',2''-Nitrilotri(ethan-1-ol)
CAS number102-71-6
EC / EINECS number203-049-8
Molecular formulaC₆H₁₅NO₃
Molar mass149.19 g/mol
AppearanceColourless to pale-yellow, viscous liquid
Common synonymsTEA, Trolamine
Melting Point21.6 °Cnear ambient -- can solidify in cool conditions
Boiling Point335.4 °Cat 1 atm
Density1.124 g/mL
Flash Point179 °C
Water SolubilityMiscible
Purity Offered99%+technical & cosmetic-grade
01 / PRODUCT DOSSIER

What Triethanolamine (TEA) is, and why buyers source it

A working overview of the compound's chemistry, its place in the aniline-derivative family, and the grades Chelora Chemicals keeps in regular supply.

Triethanolamine (TEA) carries three hydroxyethyl groups on a single tertiary amine nitrogen, the most fully substituted of the three ethanolamines in this range. We want to flag two things precisely. First, TEA has no harmonised EU CLP Annex VI entry — unlike MEA and DEA elsewhere in our range, its classification is self-classification only, and we found that self-classification genuinely varies between notifiers: some commercial SDS list only eye irritation (H319), while Japan's NITE government classification lists a broader profile including skin irritation, sensitisation, and respiratory irritation. We show the broader, more conservative NITE-based profile and flag the narrower alternative rather than quietly pick the lighter one. Second, TEA's own IARC evaluation (Monograph Volume 77, 2000) places it in Group 3, not classifiable as to carcinogenicity to humans — based on inadequate human evidence and inadequate animal evidence (no tumour increase in oral/dermal rodent studies) — a categorically different and lower-concern finding than Diethanolamine's Group 2B elsewhere in this range, and we do not let the two blur together just because they share the "ethanolamine" family name.

TEA's best-documented and most specific industrial application is as a cement grinding aid, used at roughly 0.1% by weight to prevent powder agglomeration and mill-wall/ball coating during clinker grinding — confirmed across commercial grinding-aid products and peer-reviewed cement-chemistry literature. It is also widely used as a pH-adjusting agent and emulsifier in cosmetics (subject to an EU cosmetics-regulation concentration limit, detailed below), as a metalworking-fluid component, and as a component in some 2,4-D herbicide amine-salt formulations. We found TEA's once-common role in acid-gas treating (the historic 1930s-era "Girbotol" process) widely repeated in secondary literature but could not independently confirm from a clearly authoritative primary source that TEA specifically, rather than an ethanolamine generically, was that original process amine — we flag this historical claim as plausible but not independently verified, and note that TEA does not appear in either of the current gas-treating technical sources we checked, which name MEA, DEA, and MDEA as today's dominant amines.

Where it fits in the synthesis chain

We supply Triethanolamine itself as a cement-chemistry and cosmetic/personal-care intermediate. We do not manufacture or supply finished cement products, cosmetic formulations, or metalworking fluids.

Grades we supply

99%+ technical and cosmetic grades are both offered; cosmetic-grade material is supplied consistent with the EU's Annex III concentration and purity conditions for downstream formulators.

02 / MANUFACTURING ROUTE

How Triethanolamine (TEA) is made

An overview of the production route for orientation purposes. Our manufacturing partners' own process parameters and in-process controls are proprietary and are not disclosed beyond what is needed to interpret the certificate of analysis.

Triethanolamine is made industrially by reaction of ethylene oxide with aqueous ammonia, in the same reactor system used to co-produce Monoethanolamine and Diethanolamine, with a higher ethylene oxide-to-ammonia ratio favouring this fully substituted tertiary product.

The crude product is separated from its MEA/DEA co-products by distillation, then tested for purity and colour before packing.

Cosmetic-grade material is purified to a tighter specification (minimum purity, controlled secondary-amine content) consistent with the EU cosmetics-regulation conditions that apply to this compound's use in that application.

Two things we won't let blur: IARC Group 3, and an honest hazard-classification gap

We want to be precise on both counts. TEA's IARC Group 3 finding is categorically different from, and lower-concern than, Diethanolamine's Group 2B finding elsewhere in our range -- sharing the word "ethanolamine" does not mean sharing a carcinogenicity profile, and we keep the two separate. Separately, because TEA has no EU harmonised classification, different notifiers have published genuinely different self-classifications -- some narrower (eye irritation only), some broader (adding skin irritation, sensitisation, and respiratory irritation, per Japan's NITE). We show the broader profile as the more conservative, safety-first choice, and flag honestly that a given supplier's SDS may show a narrower one, rather than imply one settled, harmonised figure exists when it does not.

03 / APPLICATIONS

Industries and processes that use it

Triethanolamine (TEA) is consumed almost entirely as a synthesis intermediate. The four fields below account for most of the demand we see through our export desk.

Field 01

Cement Grinding Aid

Used at approximately 0.1% by weight in clinker grinding to prevent powder agglomeration and mill-wall/ball coating, confirmed across commercial grinding-aid products and peer-reviewed cement-chemistry literature.

Field 02

Cosmetic pH Adjuster & Emulsifier

Widely used as a pH-balancing agent and emulsifier in cosmetic and personal-care formulations, subject to EU Annex III concentration and purity conditions.

Field 03

Metalworking-Fluid & Agrochemical-Formulation Component

Used as a pH buffer/corrosion-inhibitor component in metalworking fluids, and as a component in some 2,4-D herbicide amine-salt formulations.

04 / REACTION CHEMISTRY

How the molecule is typically carried forward

Triethanolamine's chemistry centres on its three hydroxyl groups (available for esterification and surface-active derivative formation) and its basic, fully substituted tertiary nitrogen, which readily forms salts with acids and surfactant acid-heads.

Salt/soap formation (cosmetic chemistry)

The basic tertiary nitrogen neutralises fatty acids and other acidic surfactant components, the basis of its pH-adjusting and emulsifying role in cosmetic formulations.

Surface adsorption (cement-chemistry role)

In cement grinding, TEA adsorbs onto freshly ground clinker particle surfaces, reducing electrostatic agglomeration and preventing coating of mill balls and walls -- a physical/surface-chemistry mechanism rather than a classic organic reaction.

05 / FAMILY COMPARISON

Triethanolamine (TEA) against its near relatives

Triethanolamine, Monoethanolamine and Diethanolamine are the three ethanolamines in this part of our range, sharing a manufacturing process but carrying three distinct hazard and regulatory profiles.

ProductCAS NumberTypically Used InNotes
Triethanolamine102-71-6Cement grinding aid; cosmetic pH adjusterThe product on this page. IARC Group 3; EU cosmetics Annex III restricted (not prohibited).
Monoethanolamine141-43-5Acid-gas treating; surfactant intermediateAlso supplied -- see its product page. Not evaluated by IARC.
Diethanolamine111-42-2Refinery gas treating; industrial surfactant/metalworking-fluid intermediateAlso supplied -- see its product page. IARC Group 2B; EU cosmetics Annex II prohibited.

Exact physical constants and purity specifications are confirmed per batch on the certificate of analysis — treat the notes above as a sourcing guide rather than a specification sheet.

06 / HAZARD & HANDLING

Safety classification at a glance

Based on GHS classification as commonly listed for this substance. This is a summary for orientation only — always work from the current safety data sheet supplied with your specific batch.

H315

Causes skin irritation.

H317

May cause an allergic skin reaction.

H319

Causes serious eye irritation.

H335

May cause respiratory irritation.

Signal word

Warning

Triethanolamine has no harmonised EU CLP Annex VI entry -- its classification is self-classification only, and we found this genuinely varies between notifiers. We show Japan's NITE government classification (H315/H317/H319/H335, signal word Warning) as the broader, more conservative profile; some commercial SDS list only H319 (eye irritation), a materially narrower profile. We flag this honestly rather than imply one settled figure where none exists -- check your specific supplier's current SDS for the classification they apply. IARC evaluated this substance (Monograph Vol. 77, 2000) and placed it in Group 3, not classifiable as to carcinogenicity to humans, based on inadequate human and animal evidence -- a materially different and lower-concern finding than Diethanolamine's Group 2B elsewhere in our range. EU Cosmetics Regulation Annex III (entry 62) restricts, but does not prohibit, its use in cosmetics: maximum 2.5% concentration, minimum 99% purity, maximum 0.5% secondary-amine content, and a requirement not to use with nitrosating systems.

07 / STORAGE & SHELF LIFE

Keeping it on spec between delivery and use

General storage guidance for this grade. Site-specific storage rules, segregation requirements and re-test intervals should follow your own EHS procedures and the MSDS issued with your batch.

Shelf Life24 months, unopened
Storage Temp20–30 °C (above its ~21.6 °C melting point)
ContainerDrums or IBCs, tightly sealed

Store in a cool, well-ventilated area, consistent with a mild-irritant, non-flammable-at-ambient-handling-temperature liquid. Note it can solidify just below ambient temperature (melting point 21.6 °C) in cooler storage conditions.

08 / PACKING & EXPORT

How it ships from Indonesia

Standard packing and export terms for this product. Confirm exact figures against your order — they vary slightly by destination and quantity.

Standard Packing220 kg drums
Bulk PackingIBC / ISO tank
Min. OrderFrom 1 drum
Lead Time2 – 4 weeks
Export TermsFOB · CFR · CIF
09 / QUALITY & DOCUMENTATION

What travels with every batch

Specification is agreed before the purchase order, not discovered on arrival. Every shipment of Triethanolamine (TEA) leaves with a documented, checkable paper trail.

Doc 01

Certificate of Analysis

Batch-wise assay (by GC), isomer purity, melting point range and moisture, issued against the agreed specification so your QC team can check it, not just file it.

Doc 02

Safety Data Sheet

GHS-format SDS in English covering hazard classification, handling, storage, first-aid and spill response for the exact grade shipped.

Doc 03

Technical Data Sheet

Reference physical and chemical properties, recommended storage and typical applications, for internal circulation to your process or R&D teams.

Doc 04

Certificate of Origin

Confirms Indonesian origin for customs clearance and any preferential-duty claim at your destination port.

Doc 05

Dangerous Goods Declaration

UN packing group, classification and shipper's declaration prepared ahead of loading so documentation never holds up customs.

Doc 06

Third-Party Inspection

Independent pre-shipment inspection and re-sampling can be arranged on request, at your cost, for buyers who require it as a matter of policy.

10 / FAQ

Frequently asked questions

What buyers most often ask our sales desk about this grade.

01What is Triethanolamine (TEA) used for?+
Triethanolamine is used as a cement grinding aid, as a pH-adjusting agent and emulsifier in cosmetic formulations, and as a metalworking-fluid and agrochemical-formulation component.
02What is the CAS number of Triethanolamine (TEA)?+
Its CAS Registry Number is 102-71-6, with EC number 203-049-8, molecular formula C₆H₁₅NO₃ and a molar mass of 149.19 g/mol.
03What purity grades does Chelora Chemicals supply?+
We supply technical grade and high-purity grade — the exact figures are shown in the specification rail at the top of this page. Each batch ships with a certificate of analysis stating assay, isomer purity and moisture against the agreed specification.
04Is Triethanolamine (TEA) hazardous?+
Yes. It carries the GHS signal word Warning with the hazard statements listed in the hazard section of this page. It should be handled with appropriate PPE and in line with the safety data sheet supplied with each shipment.
05Is this compound a carcinogen, like Diethanolamine?+
No -- and this is worth being precise about. IARC separately evaluated Triethanolamine and placed it in Group 3, not classifiable as to carcinogenicity to humans, based on inadequate evidence in both humans and animals. This is a categorically different, lower-concern finding than Diethanolamine's Group 2B classification elsewhere in our range, and sharing the "ethanolamine" family name doesn't mean sharing that profile.
06Why doesn't this page show one definite hazard classification like your other products?+
Because, honestly, none exists at the EU-harmonised level for this compound -- its classification is self-classification only, and different notifiers have published genuinely different profiles. We show the broader, more conservative one and flag that a narrower alternative also circulates, rather than imply a false certainty.
07Can this be used in cosmetics?+
Yes, under EU Cosmetics Regulation Annex III conditions: a maximum 2.5% concentration, minimum purity, and limits on secondary-amine and nitrosamine content. This is a restriction, not a prohibition -- a meaningfully different, less severe status than Diethanolamine's outright Annex II prohibition.
08What packing options are available?+
Standard packing is 220 kg drums, with ibc / iso tank available for bulk orders. Trial quantities from a single drum can usually be arranged before you commit to larger volumes.
09How long does delivery take?+
Typical lead time is two to four weeks plus transit, depending on whether the grade is ex-stock or made to order and your destination port. A firm date is confirmed in the written quotation.
10Can I get a sample before placing a bulk order?+
Yes. Pre-shipment samples and a batch certificate of analysis can be arranged so your QC team can verify the specification before committing to volume.
11How is Triethanolamine (TEA) manufactured?+
Ethylene oxide and ammonia Reaction of ethylene oxide with aqueous ammonia, co-produced with monoethanolamine and diethanolamine, with process conditions tuned to favour this fully substituted product is the usual industrial route, followed by washing and distillation or recrystallisation before packing.
12What is the shelf life, and how should it be stored?+
Typical shelf life is around 24 months in original, unopened packaging stored as described in the storage section of this page. If a batch is held beyond its shelf life, we recommend re-checking assay and moisture before use.
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