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Dye Intermediate · CAS 88-51-7

2B Acid

C7H8ClNO3S Molar mass 221.66 g/mol

2B Acid is a pigment-grade aminosulfonic acid used as a diazo component in Red 2B / Red Lake C-type pigment manufacture — a name we want to flag carries genuine ambiguity in parts of the dye trade, which is why we state our exact identification plainly before anything else.

Identification Sheet REP.
IUPAC name2-Amino-4-chloro-5-methylbenzenesulfonic acid
CAS number88-51-7
EC / EINECS numberNot independently confirmed
Molecular formulaC₇H₈ClNO₃S
Molar mass221.66 g/mol
AppearanceWhite to buff crystalline powder
Common synonyms2-Amino-4-chloro-5-methylbenzenesulfonic acid
Chemical TypeAminosulfonic acid, free acid formdiazotisable pigment intermediate
Melting Point>300 °Cdecomposes rather than melting cleanly
Purity Offered95% / 98%technical & dye-grade
Transport ClassificationUN 3261, Class 8, PG IIIcorrosive solid, acidic
Water Solubilitysoluble as the sodium salt; limited as free acidsee note
Form TradedFree sulfonic acid (solid powder)not a stabilised diazonium salt
01 / PRODUCT DOSSIER

What 2B Acid is, and why buyers source it

A working overview of the compound's chemistry, its place in the aniline-derivative family, and the grades Chelora Chemicals keeps in regular supply.

We need to be direct about something before describing this product: "2B Acid" is not a universally single, unambiguous name across the global dye and pigment trade. The identification we supply under this name — 2-amino-4-chloro-5-methylbenzenesulfonic acid, CAS 88-51-7 — is well corroborated: it appears as a named synonym on independent chemical databases and is carried under this exact trade name by established pigment-intermediate manufacturers. We flag this ambiguity openly rather than let a buyer assume the name alone guarantees an identical product from every supplier — always confirm CAS number 88-51-7 on your purchase order and certificate of analysis.

Chemically, this is an aromatic aminosulfonic acid: an amino group available for diazotisation, a sulfonic acid group that confers water solubility (particularly as its sodium salt) and that becomes part of the finished pigment structure, and a chlorine and methyl group that fix its substitution pattern. Diazotised and coupled onto an appropriate naphthol-type coupling component, it builds the azo chromophore behind Red 2B and related Red Lake C-type pigment chemistry — a well-established, long-standing pigment family distinct from the Naphthol-AS azoic dyeing process used directly on cotton fibre.

Where it fits in the synthesis chain

We supply the free sulfonic acid itself, ready for diazotisation at the pigment manufacturer's own facility. We do not manufacture or supply the finished Red 2B / Red Lake C pigment.

Grades we supply

95% and 98% grades are both seen across the trade; pigment manufacturers specifying consistent shade typically require the higher grade to limit isomeric and inorganic-salt carryover.

02 / MANUFACTURING ROUTE

How 2B Acid is made

An overview of the production route for orientation purposes. Our manufacturing partners' own process parameters and in-process controls are proprietary and are not disclosed beyond what is needed to interpret the certificate of analysis.

2B Acid is made by sulfonation of a suitably chlorinated toluidine, or alternatively by a nitration-reduction-sulfonation sequence on a chlorotoluene starting material, giving the amino, sulfonic acid, chlorine and methyl substitution pattern in one molecule.

The sulfonation step is run under controlled conditions to achieve the correct ring position for the sulfonic acid group, since the final pigment's shade and fastness properties depend on getting this substitution pattern right, not just on overall purity.

The crude product is purified by crystallisation, taking advantage of its very high decomposition/melting point to separate it cleanly from unreacted starting material and inorganic sulfonation by-products before drying to the free acid powder traded commercially.

Confirm the CAS number, not just the trade name

Because the dye trade's naming conventions for intermediates like this one developed historically and regionally, rather than through a single global standard, the same two or three letters and a colour reference can mean different things depending on which supplier or which decade's catalogue you're reading. We'd rather state plainly that we identify "2B Acid" as CAS 88-51-7, consistent with the strongest and most consistent sourcing we could find, and ask that buyers confirm this matches their own specification before placing a large order under this name alone.

03 / APPLICATIONS

Industries and processes that use it

2B Acid is consumed almost entirely as a synthesis intermediate. The four fields below account for most of the demand we see through our export desk.

Field 01

Red 2B / Red Lake C Pigment Manufacture

Diazotised and coupled onto an appropriate naphthol-type component to build the azo chromophore behind this established pigment family.

Field 02

Azo Pigment Intermediate Chemistry

Used more broadly wherever this specific aminosulfonic acid substitution pattern is the required diazo component.

Field 03

Pigment Lake Manufacturing

Feeds pigment-lake manufacturing processes where an aminosulfonic acid diazo component, rather than a Naphthol AS azoic base, is the correct chemistry for the target product.

04 / REACTION CHEMISTRY

How the molecule is typically carried forward

2B Acid's reaction chemistry centres on its amino group, diazotised and coupled to build the azo chromophore, while its sulfonic acid group carries through into the finished pigment structure rather than reacting further itself.

Diazotisation

Standard cold nitrous-acid diazotisation converts the amino group to a diazonium salt, the entry point to azo pigment coupling chemistry.

Azo coupling

The diazonium salt couples with an appropriate naphthol-type coupling component to build the azo chromophore that defines the finished Red 2B / Red Lake C-type pigment.

Salt formation (sulfonic acid group)

The sulfonic acid group can be converted to its sodium or other metal salt for solubility or lake-forming purposes, a standard part of pigment-lake manufacture rather than a separate synthetic step on our end.

05 / FAMILY COMPARISON

2B Acid against its near relatives

2B Acid, 4B Acid and Fast Bordeaux GP Base are the three azo/azoic dye-intermediate trade names in this part of our range — related by their shared role as diazo components in colourant manufacture, though they serve different branches of that chemistry.

ProductCAS NumberTypically Used InNotes
2B Acid88-51-7Red 2B / Red Lake C pigment manufactureThe product on this page.
4B Acid88-44-8Red/Orange 4B-type lake pigment manufactureAlso supplied — see its product page.
Fast Bordeaux GP Base96-96-8Azoic (ice-colour) diazo base for cotton dyeingAlso supplied — see its product page.

Exact physical constants and purity specifications are confirmed per batch on the certificate of analysis — treat the notes above as a sourcing guide rather than a specification sheet.

06 / HAZARD & HANDLING

Safety classification at a glance

Based on GHS classification as commonly listed for this substance. This is a summary for orientation only — always work from the current safety data sheet supplied with your specific batch.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H335

May cause respiratory irritation.

Signal word

Warning

No harmonised EU CLP Annex VI entry was located for this substance. The classification above reflects self-classification data (irritant to eyes, respiratory tract and skin) consistent across the source we could verify; it is also transport-classified as UN 3261, Class 8, Packing Group III (corrosive solid, acidic), which should be read alongside the GHS statements rather than in place of them. IARC has not evaluated this substance. We recommend checking the SDS shipped with each specific lot given the identity ambiguity flagged elsewhere on this page.

07 / STORAGE & SHELF LIFE

Keeping it on spec between delivery and use

General storage guidance for this grade. Site-specific storage rules, segregation requirements and re-test intervals should follow your own EHS procedures and the MSDS issued with your batch.

Shelf Life24 months, unopened
Storage Temp15–30 °C
ContainerFibre drums or multi-wall paper sacks with polyethylene liner

Store in a cool, dry area away from strong bases (given its acidic, corrosive character) and oxidisers. Keep containers tightly sealed to prevent moisture pickup.

08 / PACKING & EXPORT

How it ships from Indonesia

Standard packing and export terms for this product. Confirm exact figures against your order — they vary slightly by destination and quantity.

Standard Packing25 kg bags
Bulk PackingDrums / jumbo bags
Min. OrderFrom 1 drum
Lead Time2 – 4 weeks
Export TermsFOB · CFR · CIF
09 / QUALITY & DOCUMENTATION

What travels with every batch

Specification is agreed before the purchase order, not discovered on arrival. Every shipment of 2B Acid leaves with a documented, checkable paper trail.

Doc 01

Certificate of Analysis

Batch-wise assay (by GC), isomer purity, melting point range and moisture, issued against the agreed specification so your QC team can check it, not just file it.

Doc 02

Safety Data Sheet

GHS-format SDS in English covering hazard classification, handling, storage, first-aid and spill response for the exact grade shipped.

Doc 03

Technical Data Sheet

Reference physical and chemical properties, recommended storage and typical applications, for internal circulation to your process or R&D teams.

Doc 04

Certificate of Origin

Confirms Indonesian origin for customs clearance and any preferential-duty claim at your destination port.

Doc 05

Dangerous Goods Declaration

UN packing group, classification and shipper's declaration prepared ahead of loading so documentation never holds up customs.

Doc 06

Third-Party Inspection

Independent pre-shipment inspection and re-sampling can be arranged on request, at your cost, for buyers who require it as a matter of policy.

10 / FAQ

Frequently asked questions

What buyers most often ask our sales desk about this grade.

01What is 2B Acid used for?+
2B Acid is used as a diazo component in Red 2B / Red Lake C-type pigment manufacture, diazotised and coupled onto a naphthol-type coupling partner to build the finished pigment's azo chromophore.
02What is the CAS number of 2B Acid?+
Its CAS Registry Number is 88-51-7, with EC number Not independently confirmed, molecular formula C₇H₈ClNO₃S and a molar mass of 221.66 g/mol.
03What purity grades does Chelora Chemicals supply?+
We supply technical grade and high-purity grade — the exact figures are shown in the specification rail at the top of this page. Each batch ships with a certificate of analysis stating assay, isomer purity and moisture against the agreed specification.
04Is 2B Acid hazardous?+
Yes. It carries the GHS signal word Warning with the hazard statements listed in the hazard section of this page. It should be handled with appropriate PPE and in line with the safety data sheet supplied with each shipment.
05Is "2B Acid" always the same chemical everywhere in the trade?+
We want to be honest: not with absolute certainty. We identify it as CAS 88-51-7 (2-amino-4-chloro-5-methylbenzenesulfonic acid), the best-corroborated identity across independent sources and matching established suppliers' own "2B Acid" product lines. But trade names in the dye industry can vary by region and supplier history, so we recommend confirming CAS 88-51-7 against your own specification before placing a large order under this name alone.
06Do you supply the finished Red 2B pigment?+
No. We supply this aminosulfonic acid intermediate. The diazotisation and coupling chemistry that produces finished Red 2B / Red Lake C-type pigment is carried out by pigment manufacturers downstream of us.
07Is this the same kind of product as Fast Bordeaux GP Base?+
Related but not the same kind of chemistry. Fast Bordeaux GP Base is a Naphthol AS-type azoic diazo base used directly on cotton fibre in ice-colour dyeing; 2B Acid is an aminosulfonic acid used in pigment-lake manufacture, a different branch of azo colourant chemistry.
08What packing options are available?+
Standard packing is 25 kg bags, with drums / jumbo bags available for bulk orders. Trial quantities from a single drum can usually be arranged before you commit to larger volumes.
09How long does delivery take?+
Typical lead time is two to four weeks plus transit, depending on whether the grade is ex-stock or made to order and your destination port. A firm date is confirmed in the written quotation.
10Can I get a sample before placing a bulk order?+
Yes. Pre-shipment samples and a batch certificate of analysis can be arranged so your QC team can verify the specification before committing to volume.
11How is 2B Acid manufactured?+
A chlorinated toluidine or chlorotoluene precursor Sulfonation of a chlorinated toluidine, or nitration-reduction-sulfonation of a chlorotoluene precursor is the usual industrial route, followed by washing and distillation or recrystallisation before packing.
12What is the shelf life, and how should it be stored?+
Typical shelf life is around 24 months in original, unopened packaging stored as described in the storage section of this page. If a batch is held beyond its shelf life, we recommend re-checking assay and moisture before use.
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