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Alkylbenzene · CAS 100-41-4

Ethylbenzene

C6H5C2H5 Molar mass 106.17 g/mol

The ethyl-substituted aromatic supplied by Chelora Chemicals — almost entirely a single-purpose feedstock, converted by catalytic dehydrogenation into styrene monomer for the polystyrene, SBR and ABS industries — exported from Indonesia in drums or ISO tanks with full batch documentation on every shipment.

Identification Sheet REP.
IUPAC nameEthylbenzene
CAS number100-41-4
Molecular formulaC₆H₅C₂H₅
Molar mass106.17 g/mol
AppearanceColourless liquid, gasoline-like odour
Common synonymsEthylbenzene, Phenylethane, EB
Melting Point−95 °Clit.
Boiling Point136 °Cat 1 atm
Specific Gravity0.867at 20 °C
Flash Point15 °Cclosed cup
AppearanceColourless liquidgasoline/aromatic-like odour
Purity Offered99.5% / 99.9%+ (styrene grade)technical & high-purity, liquid
01 / PRODUCT DOSSIER

What Ethylbenzene is, and why buyers source it

A working overview of the compound's chemistry, its role as a single-purpose styrene feedstock, and the grades Chelora Chemicals keeps in regular supply.

Ethylbenzene is a benzene ring carrying a single ethyl substituent. Structurally it is a close cousin of the xylenes — it shares their C8H10 formula's molecular weight class and boils in the same narrow range, so it is always present as a minor component of the mixed C8 aromatic stream — but almost the entire world production of ethylbenzene is made on purpose, by direct alkylation, rather than separated from that stream.

At room temperature it is a colourless, highly flammable liquid with a gasoline-like aromatic odour, immiscible with water but miscible with most organic solvents. Its chemistry is dominated by one reaction above all others: catalytic dehydrogenation of the ethyl side chain to a vinyl group, which is essentially the entire reason ethylbenzene is manufactured at industrial scale.

Where it fits in the synthesis chain

Ethylbenzene's use is overwhelmingly single-purpose: well over 99% of production is converted directly into styrene monomer by catalytic dehydrogenation, making it, in practical terms, an intermediate step rather than a finished product. A small remaining share is used as a solvent or, in a parallel route, co-oxidised with propylene to make styrene and propylene oxide together (the POSM/SMPO process).

Grades we supply

Chelora Chemicals offers Ethylbenzene in technical grade (≈99.5% assay) for general solvent use, and styrene grade (99.9%+, tightly controlled for sulfur and other dehydrogenation-catalyst poisons) for styrene monomer manufacture. Both grades are supplied with a batch-wise certificate of analysis.

02 / MANUFACTURING ROUTE

How Ethylbenzene is made

An overview of the production route for orientation purposes. Our manufacturing partners' own process parameters and in-process controls are proprietary and are not disclosed beyond what is needed to interpret the certificate of analysis.

Ethylbenzene is manufactured by the Friedel-Crafts alkylation of benzene with ethylene: benzene + C₂H₄ → C₆H₅C₂H₅, run in either the liquid or vapour phase over a zeolite catalyst (modern plants predominantly use vapour-phase zeolite processes such as the Mobil-Badger process). The reaction is typically run with excess benzene to limit over-alkylation to diethylbenzene, which is separated and recycled back to extinction by transalkylation with fresh benzene.

Why on-purpose alkylation dominates over separation

Because ethylbenzene makes up only a small fraction of the mixed C8 aromatic stream and boils almost identically to para-xylene, separating it out would be both low-yielding and technically difficult; direct alkylation of benzene with ethylene, a widely available petrochemical olefin, is far more efficient and is why essentially all commercial ethylbenzene is made this way rather than recovered from reformate or pygas.

03 / APPLICATIONS

Industries and processes that use it

Ethylbenzene is consumed almost entirely by styrene monomer manufacture, with a small remaining share used as a solvent. The field below accounts for the overwhelming majority of the demand we see through our export desk.

Field 01

Styrene Monomer Feedstock

Catalytically dehydrogenated to styrene monomer, the dominant, near-exclusive industrial use of ethylbenzene worldwide.

Field 02

Propylene Oxide Co-Product Route (POSM/SMPO)

Used, via its hydroperoxide, in the alternative co-production route that yields both styrene monomer and propylene oxide.

Field 03

Industrial Solvent

Used in a small remaining share as a gasoline-like aromatic solvent in select industrial formulations.

Field 04

Polystyrene & SBR Chain

Supplies, through styrene monomer, the feedstock for polystyrene, ABS, SAN resins and styrene-butadiene rubber.

04 / REACTION CHEMISTRY

How the molecule is typically carried forward

The ethyl side chain's ability to lose hydrogen and form a vinyl group governs almost all of this molecule's further reaction chemistry. Reaction classes below account for most of the ways Ethylbenzene is converted into a finished product or intermediate.

Catalytic Dehydrogenation (to Styrene)

The ethyl side chain loses hydrogen over an iron-oxide catalyst in the presence of steam at high temperature, giving styrene monomer directly: C₆H₅C₂H₅ → C₆H₅CH=CH₂ + H₂.

Oxidation to Ethylbenzene Hydroperoxide

In the co-product route, ethylbenzene is first air-oxidised to its hydroperoxide, which then epoxidises propylene to propylene oxide while being reduced toward styrene.

Friedel-Crafts Alkylation (Upstream)

Benzene and ethylene combine over an acid or zeolite catalyst to form ethylbenzene itself, the first step in the whole chain.

Transalkylation of Diethylbenzene

Polyalkylated by-product diethylbenzene is reacted with fresh benzene to redistribute ethyl groups and recover additional ethylbenzene.

05 / RELATED BUILDING BLOCKS

Ethylbenzene against other amines we supply

Buyers sourcing Ethylbenzene for styrene manufacture or solvent use often need the downstream monomer or a related aromatic. A quick reference to what else is on our regular supply list.

ProductCAS NumberCategoryNotes
Ethylbenzene100-41-4Alkylbenzene (C8)The product on this page — almost entirely a single-purpose styrene monomer feedstock.
Styrene Monomer100-42-5Vinyl aromatic monomerThe direct downstream dehydrogenation product — see its product page.
Mixed Xylenes1330-20-7C8 aromatic isomer blendA related, co-boiling C8 aromatic stream — see its product page.
Cumene98-82-8Alkylbenzene (C9)A related benzene alkylate made by an analogous Friedel-Crafts route — see its product page.

Exact physical constants and purity specifications are confirmed per batch on the certificate of analysis — treat the notes above as a sourcing guide, not a specification sheet, for products other than Ethylbenzene.

06 / HAZARD & HANDLING

Safety classification at a glance

Based on GHS classification as commonly listed for this substance. This is a summary for orientation only — always work from the current safety data sheet supplied with your specific batch.

H225

Highly flammable liquid and vapour.

H304

May be fatal if swallowed and enters airways.

H332

Harmful if inhaled.

H373

May cause organ damage (hearing organs) through prolonged or repeated exposure.

PPE Standard

Chemical-resistant gloves, splash goggles and suitable respiratory protection are the baseline for routine handling.

Fire Precaution

Keep away from heat, sparks and open flame; ground and bond containers during transfer given the low flash point.

Aspiration Note

Never siphon by mouth or induce vomiting if swallowed — aspiration into the lungs is a serious hazard.

Signal word

Danger — GHS02 flammable, GHS07 harmful and GHS08 health-hazard pictograms apply.

This compound is a highly flammable liquid that may be fatal if swallowed and enters the airways, is harmful if inhaled, and may cause organ damage through prolonged or repeated exposure. It must be handled with chemical-resistant gloves, splash-proof eye protection, suitable respiratory protection and kept well away from heat and open flame. Full first-aid, storage, spill and PPE guidance is in the MSDS issued with every shipment, and should be read in full before this material is handled.

07 / STORAGE & SHELF LIFE

Keeping it on spec between delivery and use

General storage guidance for this grade. Site-specific storage rules, segregation requirements and re-test intervals should follow your own EHS procedures and the MSDS issued with your batch.

Storage TemperatureCool, ambient, below 25 °C
ContainerSealed drums / ISO tank
Typical Shelf Life24 months, unopened
Keep Away FromHeat, open flame, strong oxidizers
Beyond Shelf LifeRe-assay before use

Store in a cool, dry, well-ventilated area away from heat sources, open flame and strong oxidizing agents, in tightly closed original packaging. Ground and bond all equipment during bulk transfer given the low flash point. If a batch is held past its retest date, re-check assay, sulfur content and colour before use.

08 / PACKING & EXPORT

How it ships from Indonesia

Standard packing and export terms for this product. Confirm exact figures against your order — they vary slightly by destination and quantity.

Standard Packing200 L drums (liquid)
Bulk PackingISO tank / tanker on request
Min. OrderFrom 1 tonne
Lead Time2 – 3 weeks
Export TermsFOB · CFR · CIF
09 / QUALITY & DOCUMENTATION

What travels with every batch

Specification is agreed before the purchase order, not discovered on arrival. Every shipment of Ethylbenzene leaves with a documented, checkable paper trail.

Doc 01

Certificate of Analysis

Batch-wise assay (by titration/GC), colour and relevant physical constants, issued against the agreed specification so your QC team can check it, not just file it.

Doc 02

Safety Data Sheet

GHS-format SDS in English covering hazard classification, handling, storage, first-aid and spill response for the exact grade of Ethylbenzene shipped.

Doc 03

Technical Data Sheet

Reference physical and chemical properties, recommended storage and typical applications, for internal circulation to your process or R&D teams.

Doc 04

Certificate of Origin

Confirms Indonesian origin for customs clearance and any preferential-duty claim at your destination port.

Doc 05

Dangerous Goods Declaration

UN packing group, classification and shipper's declaration prepared ahead of loading so documentation never holds up customs.

Doc 06

Third-Party Inspection

Independent pre-shipment inspection and re-sampling can be arranged on request, at your cost, for buyers who require it as a matter of policy.

10 / FAQ

Frequently asked questions

What buyers most often ask our sales desk about this grade.

01What is Ethylbenzene used for?+
Almost entirely as the feedstock for styrene monomer, produced by catalytic dehydrogenation; a small remaining share is used as an industrial solvent.
02What is the CAS number of Ethylbenzene?+
Its CAS Registry Number is 100-41-4, with molecular formula C₆H₅C₂H₅ and a molar mass of 106.17 g/mol.
03How is Ethylbenzene made?+
By Friedel-Crafts alkylation of benzene with ethylene over a zeolite catalyst, typically in the vapour phase, with excess benzene recycled via transalkylation of the diethylbenzene by-product.
04What purity grades does Chelora Chemicals supply?+
We supply technical grade (around 99.5% assay) for general solvent use, and styrene grade (99.9%+) for styrene monomer manufacture. Each batch ships with a certificate of analysis.
05Is Ethylbenzene hazardous?+
Yes. It is a highly flammable liquid that may be fatal if swallowed and enters the airways, is harmful if inhaled, and may cause organ damage through prolonged or repeated exposure. It must be handled with the PPE and fire precautions specified in the MSDS supplied with each shipment.
06Why is almost all ethylbenzene made by alkylation rather than separated from xylenes?+
Ethylbenzene makes up only a small fraction of the mixed C8 aromatic stream and boils almost identically to para-xylene, so separating it out would be low-yielding and technically difficult; alkylating benzene directly with ethylene is far more efficient.
07What packing options are available?+
Standard packing is 200 L drums for the liquid, with ISO tank or tanker shipment available on request for bulk quantities.
08How long does delivery take?+
Typical lead time is two to three weeks plus transit, depending on whether the grade is ex-stock or made to order and your destination port. A firm date is confirmed in the written quotation.
09Can I get a sample before placing a bulk order?+
Yes. Pre-shipment samples and a batch certificate of analysis can be arranged so your QC team can verify the specification before committing to volume.
10Do you supply styrene monomer as well?+
Yes, we also supply Styrene Monomer, the direct downstream dehydrogenation product of ethylbenzene, along with Mixed Xylenes and Cumene.
Request This Grade

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