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Aliphatic Diamine · CAS 109-76-2

1,3-Propanediamine

H2N(CH2)3NH2 Molar mass 74.12 g/mol

The three-carbon straight-chain diamine supplied by Chelora Chemicals — a fast-reacting aliphatic diamine used as an epoxy curing agent, chelating-agent intermediate and polymer building block — exported from Indonesia as a liquid in drums or ISO tanks with full batch documentation on every shipment.

Identification Sheet REP.
IUPAC namePropane-1,3-diamine
CAS number109-76-2
Molecular formulaH₂N(CH₂)₃NH₂
Molar mass74.12 g/mol
AppearanceColourless to pale yellow liquid
Common synonyms1,3-Propanediamine, 1,3-Diaminopropane, Trimethylenediamine
Melting Point−12 °Clit.
Boiling Point135 – 140 °Cat 1 atm
Specific Gravity0.888at 25 °C
Flash Point34 °Cclosed cup, approx.
AppearanceColourless to pale yellow liquidhygroscopic, amine odour
Purity Offered99% / 99.5%+technical & high-purity, liquid
01 / PRODUCT DOSSIER

What 1,3-Propanediamine is, and why buyers source it

A working overview of the compound's chemistry, its role as a short-chain, fast-reacting diamine, and the grades Chelora Chemicals keeps in regular supply.

1,3-Propanediamine is a short, three-carbon straight-chain diamine: two primary amine groups separated by a single methylene spacer at the centre of the chain. The short backbone keeps both amines close together and highly reactive, giving the molecule fast reaction kinetics in condensation, addition and chelation chemistry compared with longer-chain diamines.

At room temperature it is a colourless to pale-yellow, hygroscopic liquid with a sharp amine odour, fully miscible with water and most polar organic solvents. It is a strong base and absorbs carbon dioxide and moisture readily from air, so containers are kept tightly closed between uses.

Where it fits in the synthesis chain

1,3-Propanediamine is used as a fast-curing aliphatic hardener for epoxy resin systems, as a building block for chelating agents and complexing compounds, and as an intermediate in pharmaceutical, agrochemical and specialty-surfactant synthesis. Its short, symmetrical backbone also makes it a useful monomer for polyamide and polyurea specialty polymers where a compact diamine spacer is required.

Grades we supply

Chelora Chemicals offers 1,3-Propanediamine in technical grade (≈99% assay) for general curing-agent and intermediate use, and high-purity grade (99.5%+) for pharmaceutical and chelating-agent synthesis sensitive to colour and trace-impurity content. Both grades are supplied with a batch-wise certificate of analysis.

02 / MANUFACTURING ROUTE

How 1,3-Propanediamine is made

An overview of the production route for orientation purposes. Our manufacturing partners' own process parameters and in-process controls are proprietary and are not disclosed beyond what is needed to interpret the certificate of analysis.

1,3-Propanediamine is manufactured industrially by catalytic hydrogenation of malononitrile, in which both nitrile groups of the two-carbon dinitrile are reduced to primary amines over a Raney nickel or cobalt catalyst under hydrogen pressure, typically with ammonia added to suppress secondary-amine formation: NC–CH₂–CN + 4 H₂ → H₂N(CH₂)₃NH₂. An alternative route hydrogenates 3-aminopropionitrile, itself made by Michael addition of ammonia to acrylonitrile, to the same diamine.

Why hydrogenation of a dinitrile or aminonitrile is standard

Both routes build the amine from readily available, large-scale petrochemical feedstocks — acrylonitrile and malononitrile are produced at significant industrial scale for other downstream uses — and both deliver the diamine in a single or two-step catalytic hydrogenation that is well understood and controllable for colour and purity.

03 / APPLICATIONS

Industries and processes that use it

1,3-Propanediamine is consumed across epoxy curing, chelating-agent manufacture and specialty organic synthesis, where its short, fast-reacting diamine backbone is the main draw. The fields below account for most of the demand we see through our export desk.

Field 01

Epoxy Resin Curing Agent

Used as a fast, low-viscosity aliphatic hardener for ambient-cure epoxy coatings, adhesives and flooring systems.

Field 02

Chelating Agent Intermediate

A key building block for nitrogen-based chelating and complexing agents used in water treatment and metal-finishing chemistry.

Field 03

Pharmaceutical & Agrochemical Intermediate

Supplies the short diamine spacer required in a range of active-ingredient and agrochemical synthesis routes.

Field 04

Polyamide & Polyurea Monomer

Used as a compact diamine monomer wherever specialty polyamide or polyurea chemistry calls for a three-carbon spacer.

04 / REACTION CHEMISTRY

How the molecule is typically carried forward

The two terminal primary amines, held close together by the short three-carbon backbone, govern almost all of this molecule's further reaction chemistry. Reaction classes below account for most of the ways 1,3-Propanediamine is converted into a finished product or intermediate.

Epoxide Ring-Opening (Curing)

Each terminal amine opens an epoxide ring in turn, crosslinking epoxy resin into a thermoset network at a faster rate than longer-chain diamines.

Chelate Ring Formation

Both nitrogen atoms coordinate to a metal centre, forming a five-membered chelate ring that is the basis of its use in chelating-agent synthesis.

Reductive Amination & Acylation

Reacts with aldehydes, ketones or acyl chlorides to build more complex nitrogen-containing intermediates for pharma and agrochemical routes.

Salt Formation

Forms stable, crystalline salts with mineral and organic acids, a step often used to purify or formulate downstream intermediates.

05 / RELATED BUILDING BLOCKS

1,3-Propanediamine against other amines we supply

Buyers sourcing 1,3-Propanediamine for curing or chelating-agent chemistry often need a related diamine with a different chain length or ring structure. A quick reference to what else is on our regular supply list.

ProductCAS NumberCategoryNotes
1,3-Propanediamine109-76-2Three-carbon diamineThe product on this page — a fast-reacting short-chain diamine.
Hexamethylenediamine124-09-4Six-carbon diamineA related, longer-chain diamine and the essential nylon 66 co-monomer — see its product page.
Isophorone Diamine2855-13-2Cycloaliphatic diamineA related cycloaliphatic diamine used as a premium epoxy curing agent — see its product page.
Piperazine110-85-0Cyclic diamineA related cyclic diamine used across pharma and membrane chemistry — see its product page.

Exact physical constants and purity specifications are confirmed per batch on the certificate of analysis — treat the notes above as a sourcing guide, not a specification sheet, for products other than 1,3-Propanediamine.

06 / HAZARD & HANDLING

Safety classification at a glance

Based on GHS classification as commonly listed for this substance. This is a summary for orientation only — always work from the current safety data sheet supplied with your specific batch.

H226

Flammable liquid and vapour.

H302

Harmful if swallowed.

H314

Causes severe skin burns and eye damage.

H335

May cause respiratory irritation.

PPE Standard

Impervious gloves, chemical splash goggles or a face shield, and suitable respiratory protection are the baseline for routine handling.

Fire Precaution

Keep away from heat, sparks and open flame; ground and bond containers during transfer.

Hygroscopic Handling

Keep containers tightly closed between uses to limit moisture and CO₂ pickup.

Signal word

Danger — GHS02 flammable, GHS05 corrosive and GHS07 harmful pictograms apply.

This compound is a flammable liquid that causes severe skin burns and eye damage, may cause respiratory irritation, and is harmful if swallowed. It must be handled with impervious gloves, splash-proof eye protection and suitable respiratory protection, and kept away from heat and open flame. Full first-aid, storage, spill and PPE guidance is in the MSDS issued with every shipment, and should be read in full before this material is handled.

07 / STORAGE & SHELF LIFE

Keeping it on spec between delivery and use

General storage guidance for this grade. Site-specific storage rules, segregation requirements and re-test intervals should follow your own EHS procedures and the MSDS issued with your batch.

Storage TemperatureCool, ambient, below 30 °C
ContainerSealed drums / ISO tank
Typical Shelf Life24 months, unopened
Keep Away FromHeat, strong oxidizers, strong acids
Beyond Shelf LifeRe-assay before use

Store in a cool, dry, well-ventilated area away from heat sources, strong oxidizing agents and strong acids, in tightly closed original packaging. As the product is hygroscopic, minimise exposure to humid air during transfer. If a batch is held past its retest date, re-check assay, colour and water content before use.

08 / PACKING & EXPORT

How it ships from Indonesia

Standard packing and export terms for this product. Confirm exact figures against your order — they vary slightly by destination and quantity.

Standard Packing200 kg drums (liquid)
Bulk PackingISO tank / flexitank on request
Min. OrderFrom 1 tonne
Lead Time2 – 3 weeks
Export TermsFOB · CFR · CIF
09 / QUALITY & DOCUMENTATION

What travels with every batch

Specification is agreed before the purchase order, not discovered on arrival. Every shipment of 1,3-Propanediamine leaves with a documented, checkable paper trail.

Doc 01

Certificate of Analysis

Batch-wise assay (by titration/GC), colour and relevant physical constants, issued against the agreed specification so your QC team can check it, not just file it.

Doc 02

Safety Data Sheet

GHS-format SDS in English covering hazard classification, handling, storage, first-aid and spill response for the exact grade of 1,3-Propanediamine shipped.

Doc 03

Technical Data Sheet

Reference physical and chemical properties, recommended storage and typical applications, for internal circulation to your process or R&D teams.

Doc 04

Certificate of Origin

Confirms Indonesian origin for customs clearance and any preferential-duty claim at your destination port.

Doc 05

Dangerous Goods Declaration

UN packing group, classification and shipper's declaration prepared ahead of loading so documentation never holds up customs.

Doc 06

Third-Party Inspection

Independent pre-shipment inspection and re-sampling can be arranged on request, at your cost, for buyers who require it as a matter of policy.

10 / FAQ

Frequently asked questions

What buyers most often ask our sales desk about this grade.

01What is 1,3-Propanediamine used for?+
Mainly as a fast-curing aliphatic hardener for epoxy resin systems and as a building block for chelating agents; it also serves as an intermediate in pharmaceutical, agrochemical and specialty polymer synthesis.
02What is the CAS number of 1,3-Propanediamine?+
Its CAS Registry Number is 109-76-2, with molecular formula H₂N(CH₂)₃NH₂ and a molar mass of 74.12 g/mol.
03How is 1,3-Propanediamine made?+
By catalytic hydrogenation of malononitrile, or alternatively of 3-aminopropionitrile derived from acrylonitrile, over a Raney nickel or cobalt-based catalyst under hydrogen pressure.
04What purity grades does Chelora Chemicals supply?+
We supply technical grade (around 99% assay) for general curing-agent and intermediate use, and high-purity grade (99.5%+) for pharmaceutical and chelating-agent synthesis. Each batch ships with a certificate of analysis.
05Is 1,3-Propanediamine hazardous?+
Yes. It is a flammable liquid that causes severe skin burns and eye damage, may cause respiratory irritation, and is harmful if swallowed. It must be handled with the PPE and fire precautions specified in the MSDS supplied with each shipment.
06Why is 1,3-Propanediamine faster-reacting than longer-chain diamines?+
Because its two amine groups sit only three carbons apart, the molecule reacts faster and at lower viscosity than longer-chain diamines such as hexamethylenediamine, which is useful for quick-curing epoxy systems but requires tighter control of exotherm and working time.
07What packing options are available?+
Standard packing is 200 kg drums for the liquid, with ISO tank or flexitank shipment available on request for bulk quantities.
08How long does delivery take?+
Typical lead time is two to three weeks plus transit, depending on whether the grade is ex-stock or made to order and your destination port. A firm date is confirmed in the written quotation.
09Can I get a sample before placing a bulk order?+
Yes. Pre-shipment samples and a batch certificate of analysis can be arranged so your QC team can verify the specification before committing to volume.
10Do you supply other diamines as well?+
Yes, we also supply Hexamethylenediamine, Isophorone Diamine and Piperazine, related diamines with different chain lengths and ring structures.
Request This Grade

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