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Toluidine · CAS 108-44-1

Meta Toluidine

C7H9N Molar mass 107.15 g/mol

The meta toluidine isomer, supplied by Chelora Chemicals as a dye intermediate and cyanoacrylate adhesive component — exported from Indonesia with full batch documentation on every shipment.

Identification Sheet REP.
IUPAC name3-Methylaniline
CAS number108-44-1
EC / EINECS number203-583-1
Molecular formulaC₇H₉N
Molar mass107.15 g/mol
AppearanceColourless to yellow liquid
Common synonymsm-Toluidine, m-Aminotoluene
Melting Point−30 °Cliquid at ambient
Boiling Point203 – 204 °Cat 1 atm
Density0.99 g/cm³at 25 °C
Flash Point85 – 86 °Cclosed cup
Log P (o/w)1.40moderately lipophilic
Purity Offered99% / 99.5%+technical & high-purity
01 / PRODUCT DOSSIER

What Meta Toluidine is, and why buyers source it

A working overview of the compound's chemistry, its place in the aniline-derivative family, and the grades Chelora Chemicals keeps in regular supply.

Meta Toluidine places its methyl group across the ring from the amino group, in the same relative position that gives Meta Chloroaniline its character elsewhere in our range: an unhindered, fully accessible amine with none of the steric complications a neighbouring substituent would bring. It is worth stating plainly, given its close relationship to Ortho Toluidine: this substance has not been evaluated by IARC at all — that is a different thing from a Group 3 "not classifiable" finding, which at least implies a review took place. No carcinogen classification, harmonised or otherwise, was found for this substance in the sources we checked.

It is a liquid at ambient temperature, colourless to yellow when fresh and darkening on exposure to air and light, consistent with the whole toluidine family. Its freezing point of −30 °C means it stays liquid and pumpable through any normal storage or transit condition, more forgiving than its ortho relative. It is only slightly soluble in water and dissolves readily in common organic solvents.

Where it fits in the synthesis chain

Meta Toluidine is used as a dye-industry intermediate — feeding azo dyes including shades such as Allura Red AC and carmoisine-type colourants — and as a component of accelerator systems in cyanoacrylate ("super glue") adhesive formulation. It is a lower-volume isomer than ortho or para, produced as part of the same mixed toluene-nitration chemistry that supplies the family, with demand concentrated in these two established outlets.

Grades we supply

Chelora Chemicals offers Meta Toluidine in technical grade (99%) and high-purity grade (99.5%+), both with a batch-wise certificate of analysis. As with the other toluidines, isomer purity is usually the specification line that matters most to dye-industry buyers, since ortho or para carryover diazotizes and couples alongside the intended material and shows up as shade variation.

02 / MANUFACTURING ROUTE

How Meta Toluidine is made

An overview of the production route for orientation purposes. Our manufacturing partners' own process parameters and in-process controls are proprietary and are not disclosed beyond what is needed to interpret the certificate of analysis.

Meta Toluidine is made by nitrating toluene, separating the meta-nitrotoluene fraction from the dominant ortho and para isomers, and reducing it to the amine by catalytic hydrogenation or an equivalent chemical reduction.

Toluene nitration gives only a small proportion of the meta nitro isomer relative to ortho and para, so the separation step is where the real cost and difficulty of this product sits, much as it does for Meta Chloroaniline elsewhere in our range — though the underlying nitration chemistry differs between the two families.

After reduction the amine is washed and distilled to remove isomeric carryover and catalyst residues before packing.

Why isomer purity matters more here than the headline assay

Because the meta nitro isomer is the minor fraction of toluene nitration, separation quality — not the straightforward reduction step that follows — is what sets this product's real purity. Ortho or para toluidine carryover reacts right alongside the intended material in diazotization and coupling chemistry, and given how differently the ortho isomer in particular is regulated, buyers should treat the isomer purity figure on the certificate of analysis as the number that matters most.

03 / APPLICATIONS

Industries and processes that use it

Meta Toluidine is consumed almost entirely as a synthesis intermediate. The four fields below account for most of the demand we see through our export desk.

Field 01

Azo Dyes

A dye-industry intermediate for azo colourants, including dyes in the Allura Red and carmoisine shade families.

Field 02

Cyanoacrylate Adhesives

A component of accelerator systems used in cyanoacrylate ("super glue") adhesive formulation.

Field 03

General Synthesis

Used more broadly as an unhindered aromatic amine building block in organic synthesis.

04 / REACTION CHEMISTRY

How the molecule is typically carried forward

With the methyl group well away from the amino group, the nitrogen behaves much like aniline itself — the reactions below run readily and without the steric complication of the ortho isomer.

Diazotization

Nitrous acid generated in situ below 5 °C converts the amine to the diazonium salt.

Azo Coupling

The diazonium salt couples with an electron-rich aromatic partner to build the azo chromophore of a dye.

Acylation

Reaction with an acid chloride or anhydride gives the anilide, used in general intermediate synthesis.

05 / FAMILY COMPARISON

Meta Toluidine against its near relatives

The three toluidine isomers share a formula and a close structural relationship, but their regulatory status could not be more different. The table below sets that out plainly before anything else.

ProductCAS NumberTypically Used InNotes
Meta Toluidine108-44-1Dye intermediates, cyanoacrylate adhesive chemistryThe product on this page. No CMR classification found.
Ortho Toluidine95-53-4Rubber chemicals, dyes, metolachlor/acetochlorAlso supplied — see its product page. IARC Group 1, the most severe classification in our range.
Para Toluidine106-49-0Dye and pigment intermediates, adhesive chemistryAlso supplied — see its product page. EU Category 2 carcinogen.
Aniline62-53-3MDI/polyurethane, rubber chemicals, dyesThe unmethylated parent compound — see its product page.

Exact physical constants and purity specifications are confirmed per batch on the certificate of analysis — treat the notes above as a sourcing guide rather than a specification sheet.

06 / HAZARD & HANDLING

Safety classification at a glance

Based on GHS classification as commonly listed for this substance. This is a summary for orientation only — always work from the current safety data sheet supplied with your specific batch.

H301

Toxic if swallowed.

H311

Toxic in contact with skin.

H331

Toxic if inhaled.

H319

Causes serious eye irritation.

H373

May cause damage to organs through prolonged or repeated exposure.

H400

Very toxic to aquatic life.

Signal word

Danger — GHS06 toxic, GHS08 health hazard and GHS09 environment pictograms apply.

No harmonised Annex VI entry was located for this substance, so the classification above reflects registrant self-classification. It carries no carcinogen or mutagen classification, harmonised or otherwise, in the sources we checked — distinct from Ortho Toluidine's IARC Group 1 status, and worth stating clearly since the two are easily confused by name alone. It remains acutely toxic by all three exposure routes and causes organ damage on repeated exposure; handle with gloves, eye protection and adequate ventilation.

07 / STORAGE & SHELF LIFE

Keeping it on spec between delivery and use

General storage guidance for this grade. Site-specific storage rules, segregation requirements and re-test intervals should follow your own EHS procedures and the MSDS issued with your batch.

Storage TemperatureAmbient, protected from light
ContainerSealed lined drum
Typical Shelf Life24 months, unopened
Keep Away FromOxidizers, strong acids, direct light
Freezing Point−30 °C — no freezing risk

Store in a cool, dry, well-ventilated area, protected from light, in tightly closed original containers away from oxidizers and strong acids. This is the most forgiving of the toluidines to warehouse: a freezing point of −30 °C means it stays liquid and pumpable at any normal storage temperature. Expect progressive darkening on exposure to air and light; this is a colour change rather than an assay change.

08 / PACKING & EXPORT

How it ships from Indonesia

Standard packing and export terms for this product. Confirm exact figures against your order — they vary slightly by destination and quantity.

Standard Packing220 kg drums
Bulk PackingIBC / ISO tank
Min. OrderFrom 1 drum
Lead Time2 – 4 weeks
Export TermsFOB · CFR · CIF
09 / QUALITY & DOCUMENTATION

What travels with every batch

Specification is agreed before the purchase order, not discovered on arrival. Every shipment of Meta Toluidine leaves with a documented, checkable paper trail.

Doc 01

Certificate of Analysis

Batch-wise assay (by GC), isomer purity, melting point range and moisture, issued against the agreed specification so your QC team can check it, not just file it.

Doc 02

Safety Data Sheet

GHS-format SDS in English covering hazard classification, handling, storage, first-aid and spill response for the exact grade shipped.

Doc 03

Technical Data Sheet

Reference physical and chemical properties, recommended storage and typical applications, for internal circulation to your process or R&D teams.

Doc 04

Certificate of Origin

Confirms Indonesian origin for customs clearance and any preferential-duty claim at your destination port.

Doc 05

Dangerous Goods Declaration

UN packing group, classification and shipper's declaration prepared ahead of loading so documentation never holds up customs.

Doc 06

Third-Party Inspection

Independent pre-shipment inspection and re-sampling can be arranged on request, at your cost, for buyers who require it as a matter of policy.

10 / FAQ

Frequently asked questions

What buyers most often ask our sales desk about this grade.

01What is Meta Toluidine used for?+
It is used as a dye-industry intermediate for azo colourants and as a component of accelerator systems in cyanoacrylate adhesive formulation.
02What is the CAS number of Meta Toluidine?+
Its CAS Registry Number is 108-44-1, with EC number 203-583-1, molecular formula C₇H₉N and a molar mass of 107.15 g/mol.
03What purity grades does Chelora Chemicals supply?+
We supply technical grade and high-purity grade — the exact figures are shown in the specification rail at the top of this page. Each batch ships with a certificate of analysis stating assay, isomer purity and moisture against the agreed specification.
04Is Meta Toluidine hazardous?+
Yes. It carries the GHS signal word Danger with the hazard statements listed in the hazard section of this page. It should be handled with appropriate PPE and in line with the safety data sheet supplied with each shipment.
05Is this the same compound as Ortho Toluidine, just with a different name?+
No — and the distinction matters. Meta Toluidine (CAS 108-44-1) and Ortho Toluidine (CAS 95-53-4) are different isomers with very different regulatory status. Ortho Toluidine is IARC Group 1, a confirmed human carcinogen. Meta Toluidine has not been evaluated by IARC and carries no carcinogen classification from any source we checked. Always order and document by CAS number rather than by the common name alone.
06What packing options are available?+
Standard packing is 220 kg drums, with ibc / iso tank available for bulk orders. Trial quantities from a single drum can usually be arranged before you commit to larger volumes.
07How long does delivery take?+
Typical lead time is two to four weeks plus transit, depending on whether the grade is ex-stock or made to order and your destination port. A firm date is confirmed in the written quotation.
08Can I get a sample before placing a bulk order?+
Yes. Pre-shipment samples and a batch certificate of analysis can be arranged so your QC team can verify the specification before committing to volume.
09How is Meta Toluidine manufactured?+
3-Nitrotoluene, separated from the mixed nitration of toluene. Catalytic hydrogenation of 3-nitrotoluene is the usual industrial reduction, followed by washing and distillation or recrystallisation before packing.
10What is the shelf life, and how should it be stored?+
Typical shelf life is around 24 months in original, unopened packaging stored as described in the storage section of this page. If a batch is held beyond its shelf life, we recommend re-checking assay and moisture before use.
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