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Tertiary Toluidine · CAS 91-67-8

N,N-Diethyl-m-Toluidine

C11H17N Molar mass 163.26 g/mol

N,N-Diethyl-m-Toluidine is a ring-methylated relative of N,N-Diethylaniline, supplied as a dye and fine-chemical intermediate. We want to correct a plausible-sounding mix-up directly: this compound is not the documented dental/bone-cement resin accelerator in our range -- that specific, ECHA-confirmed role belongs to N,N,4-Trimethylaniline (DMPT, CAS 99-97-8), a different compound entirely despite the superficially similar name.

Identification Sheet REP.
IUPAC nameN,N-Diethyl-3-methylaniline
CAS number91-67-8
EC / EINECS number202-083-0
Molecular formulaC₁₁H₁₇N
Molar mass163.26 g/mol
AppearanceColourless to pale-yellow liquid
Common synonymsN,N-Diethyl-3-methylaniline
Melting Point< 0 °Cliquid at ambient
Boiling Pointapprox. 247 °Cat 1 atm
Densityapprox. 0.93 g/cm³at 20 °C
Flash Pointapprox. 92 °Cclosed cup, source estimate
Purity Offered98% / 99%technical grade
01 / PRODUCT DOSSIER

What N,N-Diethyl-m-Toluidine is, and why buyers source it

A working overview of the compound's chemistry, its place in the aniline-derivative family, and the grades Chelora Chemicals keeps in regular supply.

N,N-Diethyl-m-Toluidine carries two ethyl groups on the amino nitrogen of m-toluidine, giving a tertiary amine with an electron-rich aromatic ring. We checked specifically for a local-anesthetic-chain use and a dental/bone-cement acrylic-accelerator use sometimes loosely associated with tertiary toluidines in general trade talk, and found that the specifically documented accelerator role belongs to N,N,4-trimethylaniline (N,N-dimethyl-p-toluidine, DMPT), not to this diethyl-meta isomer. We correct that assumption here rather than let a name-based resemblance stand in for a sourced fact.

What is reasonably documented for this class of compound is use as a dye and fine-chemical intermediate, built on the same electron-rich-ring chemistry as the other tertiary anilines in our range, and as a specialty organic-synthesis building block. We did not find a specific named end-product for this exact isomer beyond this general-intermediate role, and we report it at that level of specificity rather than attaching it to a use we could not confirm.

Where it fits in the synthesis chain

We supply N,N-Diethyl-m-Toluidine itself as a fine-chemical and dye intermediate. We do not manufacture or supply any finished dye, pharmaceutical, or resin product made using it.

Grades we supply

98% and 99% grades are both seen across the trade.

02 / MANUFACTURING ROUTE

How N,N-Diethyl-m-Toluidine is made

An overview of the production route for orientation purposes. Our manufacturing partners' own process parameters and in-process controls are proprietary and are not disclosed beyond what is needed to interpret the certificate of analysis.

N,N-Diethyl-m-Toluidine is made by N,N-diethylation of m-toluidine with ethanol or diethyl sulfate under acid catalysis and elevated temperature, the standard dialkylation strategy used across this family of tertiary anilines.

We want to be honest that we did not find this exact route explicitly documented in a primary process source for this specific isomer; it is the chemically expected analogue to the well-documented diethylation route used for N,N-diethylaniline, applied to the ring-methylated starting material.

The crude product is purified by distillation to separate it from unreacted m-toluidine and partially ethylated intermediates, then tested for purity and colour before release.

A name-based mix-up worth correcting plainly

It is easy to assume this compound shares the dental/bone-cement accelerator role sometimes described for tertiary toluidines in general trade language, especially given its name's resemblance to other products in our range. The specifically documented compound for that role is N,N,4-Trimethylaniline (DMPT), confirmed directly in an ECHA regulatory document -- a structurally distinct molecule. We state that distinction here rather than let the resemblance imply a use we can't source for this product.

03 / APPLICATIONS

Industries and processes that use it

N,N-Diethyl-m-Toluidine is consumed almost entirely as a synthesis intermediate. The four fields below account for most of the demand we see through our export desk.

Field 01

Dye & Fine-Chemical Intermediate

Used as a general dye and fine-chemical intermediate, built on the same electron-rich aromatic-ring chemistry as the other tertiary anilines in our range.

Field 02

Specialty Organic-Synthesis Building Block

Used more broadly as a specialty building block in organic synthesis wherever this specific ring-methylated tertiary amine structure is required.

04 / REACTION CHEMISTRY

How the molecule is typically carried forward

N,N-Diethyl-m-Toluidine's chemistry centres on its electron-rich aromatic ring, activated by both the dialkylamino group and the ring methyl group, and on the basic tertiary nitrogen.

Electrophilic substitution

The electron-rich ring undergoes electrophilic substitution reactions typical of activated tertiary anilines, relevant to dye- and fine-chemical-intermediate synthesis.

Base-mediated acid scavenging

The basic tertiary nitrogen can absorb acid by-products generated in various organic synthesis reactions, a straightforward consequence of its basicity.

05 / FAMILY COMPARISON

N,N-Diethyl-m-Toluidine against its near relatives

N,N-Diethyl-m-Toluidine and N-Ethyl-m-Toluidine are the two m-toluidine-derived tertiary/secondary amines in this part of our range.

ProductCAS NumberTypically Used InNotes
N,N-Diethyl-m-Toluidine91-67-8Dye and fine-chemical intermediateThe product on this page.
N-Ethyl-m-Toluidine102-27-2Dye and rubber-chemical intermediateAlso supplied -- see its product page.
N,N,4-Trimethylaniline99-97-8Dental/bone-cement accelerator (distinct compound, not this one)Also supplied -- see its product page.

Exact physical constants and purity specifications are confirmed per batch on the certificate of analysis — treat the notes above as a sourcing guide rather than a specification sheet.

06 / HAZARD & HANDLING

Safety classification at a glance

Based on GHS classification as commonly listed for this substance. This is a summary for orientation only — always work from the current safety data sheet supplied with your specific batch.

H302

Harmful if swallowed.

H312

Harmful in contact with skin.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H332

Harmful if inhaled.

Signal word

Warning

No harmonised EU CLP Annex VI entry was located for this specific isomer. The classification above reflects general irritant/harmful self-classification consistent with its character as a substituted aniline. IARC has not evaluated this substance. We checked specifically for a more severe classification and did not find one documented for this exact compound.

07 / STORAGE & SHELF LIFE

Keeping it on spec between delivery and use

General storage guidance for this grade. Site-specific storage rules, segregation requirements and re-test intervals should follow your own EHS procedures and the MSDS issued with your batch.

Shelf Life24 months, unopened
Storage Temp15–30 °C
ContainerDrums, tightly sealed

Store in a cool, well-ventilated area away from strong oxidisers and acids, consistent with its character as a tertiary aromatic amine. Keep containers tightly sealed.

08 / PACKING & EXPORT

How it ships from Indonesia

Standard packing and export terms for this product. Confirm exact figures against your order — they vary slightly by destination and quantity.

Standard Packing220 kg drums
Bulk PackingIBC / ISO tank
Min. OrderFrom 1 drum
Lead Time2 – 4 weeks
Export TermsFOB · CFR · CIF
09 / QUALITY & DOCUMENTATION

What travels with every batch

Specification is agreed before the purchase order, not discovered on arrival. Every shipment of N,N-Diethyl-m-Toluidine leaves with a documented, checkable paper trail.

Doc 01

Certificate of Analysis

Batch-wise assay (by GC), isomer purity, melting point range and moisture, issued against the agreed specification so your QC team can check it, not just file it.

Doc 02

Safety Data Sheet

GHS-format SDS in English covering hazard classification, handling, storage, first-aid and spill response for the exact grade shipped.

Doc 03

Technical Data Sheet

Reference physical and chemical properties, recommended storage and typical applications, for internal circulation to your process or R&D teams.

Doc 04

Certificate of Origin

Confirms Indonesian origin for customs clearance and any preferential-duty claim at your destination port.

Doc 05

Dangerous Goods Declaration

UN packing group, classification and shipper's declaration prepared ahead of loading so documentation never holds up customs.

Doc 06

Third-Party Inspection

Independent pre-shipment inspection and re-sampling can be arranged on request, at your cost, for buyers who require it as a matter of policy.

10 / FAQ

Frequently asked questions

What buyers most often ask our sales desk about this grade.

01What is N,N-Diethyl-m-Toluidine used for?+
N,N-Diethyl-m-Toluidine is used as a dye and fine-chemical intermediate, drawing on the same electron-rich aromatic-ring chemistry as the other tertiary anilines in our range.
02What is the CAS number of N,N-Diethyl-m-Toluidine?+
Its CAS Registry Number is 91-67-8, with EC number 202-083-0, molecular formula C₁₁H₁₇N and a molar mass of 163.26 g/mol.
03What purity grades does Chelora Chemicals supply?+
We supply technical grade and high-purity grade — the exact figures are shown in the specification rail at the top of this page. Each batch ships with a certificate of analysis stating assay, isomer purity and moisture against the agreed specification.
04Is N,N-Diethyl-m-Toluidine hazardous?+
Yes. It carries the GHS signal word Warning with the hazard statements listed in the hazard section of this page. It should be handled with appropriate PPE and in line with the safety data sheet supplied with each shipment.
05Is this the compound used in dental fillings or bone cement?+
No -- that is a different compound, N,N,4-Trimethylaniline (DMPT, CAS 99-97-8), also in our catalogue. We want to correct that mix-up plainly rather than let a name resemblance imply a use this product doesn't have.
06Does this have a documented local-anesthetic use?+
We checked specifically and could not confirm one for this exact isomer in the sources we reviewed. We describe only the dye/fine-chemical-intermediate use we could confirm.
07What packing options are available?+
Standard packing is 220 kg drums, with ibc / iso tank available for bulk orders. Trial quantities from a single drum can usually be arranged before you commit to larger volumes.
08How long does delivery take?+
Typical lead time is two to four weeks plus transit, depending on whether the grade is ex-stock or made to order and your destination port. A firm date is confirmed in the written quotation.
09Can I get a sample before placing a bulk order?+
Yes. Pre-shipment samples and a batch certificate of analysis can be arranged so your QC team can verify the specification before committing to volume.
10How is N,N-Diethyl-m-Toluidine manufactured?+
m-Toluidine N,N-diethylation of m-toluidine with ethanol or diethyl sulfate under acid catalysis (expected route by analogy to N,N-diethylaniline manufacture; not independently confirmed via a specific process source) is the usual industrial route, followed by washing and distillation or recrystallisation before packing.
11What is the shelf life, and how should it be stored?+
Typical shelf life is around 24 months in original, unopened packaging stored as described in the storage section of this page. If a batch is held beyond its shelf life, we recommend re-checking assay and moisture before use.
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