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Dihydroxy Ether Glycol · CAS 111-46-6

Diethylene Glycol

(HOCH2CH2)2O Molar mass 106.12 g/mol

The ether-linked diol supplied by Chelora Chemicals — a co-product of ethylene oxide hydration used across unsaturated polyester resins, polyurethanes and specialty solvents — exported from Indonesia as bulk liquid with full batch documentation on every shipment.

Identification Sheet REP.
IUPAC name2,2'-Oxydiethanol
CAS number111-46-6
Molecular formulaC₄H₁₀O₃
Molar mass106.12 g/mol
AppearanceColourless, odourless, hygroscopic liquid
Common synonymsDiethylene Glycol, DEG, 2,2'-Oxydiethanol
Melting Point−10.5 °Clit.
Boiling Point245 °Cat 1 atm
Specific Gravity1.118liquid, 20 °C
Flash Point124 °Cclosed cup
AppearanceColourless, hygroscopic liquidpractically odourless
Purity Offered99.5%+industrial grade, liquid
01 / PRODUCT DOSSIER

What Diethylene Glycol is, and why buyers source it

A working overview of the compound's chemistry, its role as a co-product of the ethylene oxide/glycol chain, and the grade Chelora Chemicals keeps in regular supply.

Diethylene Glycol is a dihydroxy ether: two ethylene glycol units joined through an ether oxygen, leaving a hydroxyl group free at each end of the molecule. Those two terminal hydroxyls behave much like monoethylene glycol's own hydroxyls in esterification and polymer-forming chemistry, while the central ether linkage adds flexibility and a higher boiling point than the simpler glycol.

At room temperature it is a colourless, practically odourless, strongly hygroscopic liquid, fully miscible with water and most polar organic solvents. It is non-volatile relative to the solvents it is often blended with, which is part of why it is valued as a humectant and high-boiling solvent component.

Where it fits in the value chain

Diethylene Glycol is used directly as a flexibilising co-monomer in unsaturated polyester resin manufacture, where its ether linkage softens the cured resin network relative to one built purely on monoethylene glycol. It is also a raw material for certain polyurethane (polyester polyol) systems, a high-boiling solvent and coupling agent in printing inks, textile and paper processing, a humectant in some industrial and tobacco applications, and the feedstock for morpholine and triethylene glycol production. Historically it also saw use in natural-gas dehydration, a role now dominated by triethylene glycol.

Grade we supply

Chelora Chemicals offers Diethylene Glycol in industrial grade (99.5%+ purity) as bulk liquid, suited to unsaturated polyester resin, polyurethane and industrial solvent applications. The grade is supplied with a batch-wise certificate of analysis.

02 / MANUFACTURING ROUTE

How Diethylene Glycol is made

An overview of the production route for orientation purposes. Our manufacturing partners' own process parameters and in-process controls are proprietary and are not disclosed beyond what is needed to interpret the certificate of analysis.

Diethylene Glycol is co-produced alongside monoethylene glycol (MEG) in the industrial hydration of ethylene oxide. Ethylene oxide reacts with water in a large excess to favour the mono-adduct, monoethylene glycol, but a portion of the ethylene oxide reacts further with the MEG already formed to give diethylene glycol, and a smaller portion still reacts again to give triethylene glycol: C₂H₄O + H₂O → HOCH₂CH₂OH (MEG); HOCH₂CH₂OH + C₂H₄O → (HOCH₂CH₂)₂O (DEG).

The mixed glycol stream from the hydration reactor is purified by multi-effect evaporation to remove water, followed by vacuum fractional distillation, which separates the mixture into monoethylene glycol, diethylene glycol, triethylene glycol and heavier glycol fractions by their differing boiling points. The water-to-ethylene-oxide ratio used in the hydration step is the main lever producers use to control how much DEG (versus MEG) the plant yields.

03 / APPLICATIONS

Industries and processes that use it

Diethylene Glycol is consumed across unsaturated polyester resin, polyurethane and industrial solvent applications. The fields below account for most of the demand we see through our export desk.

Field 01

Unsaturated Polyester Resin Modifier

Used as a flexibilising co-monomer glycol in UPR manufacture, softening the cured resin network for coatings, laminates and gelcoats.

Field 02

Polyurethane Raw Material

A diol building block in certain polyester-polyol formulations used in polyurethane foam and elastomer manufacture.

Field 03

Industrial Solvent & Coupling Agent

A high-boiling, water-miscible solvent and coupling agent in printing inks, textile processing and industrial cleaning formulations.

Field 04

Feedstock for Triethylene Glycol & Morpholine

Further reacted with ethylene oxide to give triethylene glycol, or dehydrated/aminated to give morpholine, a key specialty-amine intermediate.

04 / REACTION CHEMISTRY

How the molecule is typically carried forward

The two terminal hydroxyl groups and the central ether linkage govern almost all of this molecule's further reaction chemistry. Reaction classes below account for most of the ways Diethylene Glycol is converted into a finished resin or intermediate.

Esterification

Each terminal hydroxyl reacts with a diacid (such as phthalic or maleic anhydride) to build ester linkages, contributing to the backbone of unsaturated polyester resins.

Further Ethoxylation

Reaction with additional ethylene oxide extends the chain further, giving triethylene glycol and, beyond that, tetraethylene glycol and higher polyglycols.

Polyurethane Chain Extension

The two hydroxyls react with isocyanate groups to build urethane linkages, contributing to certain polyester-polyol-based polyurethane systems.

Dehydration to Morpholine

Under acid catalysis and with ammonia, the molecule cyclises with loss of water to give morpholine, a heterocyclic amine used in rubber and corrosion-inhibitor chemistry.

05 / RELATED BUILDING BLOCKS

Diethylene Glycol against other glycols we supply

Buyers sourcing diethylene glycol for resin or polyurethane chemistry often need a related glycol with a different boiling point or hydroxyl functionality. A quick reference to what else is on our regular supply list.

ProductCAS NumberCategoryNotes
Diethylene Glycol111-46-6Ether diol (C2 glycol dimer)The product on this page — a flexibilising co-monomer glycol for unsaturated polyester resins.
Triethylene Glycol112-27-6Ether diol (C2 glycol trimer)A related, higher-boiling glycol and the standard natural-gas dehydration fluid — see its product page.
Mono Propylene Glycol57-55-6C3 glycolA related glycol from propylene oxide hydration, widely used in food and pharma-grade applications — see its product page.
Propylene Oxide75-56-9Alkylene oxideThe epoxide precursor to propylene glycol, analogous to ethylene oxide's role in this molecule's own manufacture — see its product page.

Exact physical constants and purity specifications are confirmed per batch on the certificate of analysis — treat the notes above as a sourcing guide, not a specification sheet, for products other than Diethylene Glycol.

06 / HAZARD & HANDLING

Safety classification at a glance

Based on GHS classification as commonly listed for this substance. This is a summary for orientation only — always work from the current safety data sheet supplied with your specific batch.

H302

Harmful if swallowed.

H373

May cause damage to organs (kidneys) through prolonged or repeated exposure.

Combustible Liquid

Combustible at elevated temperature; not classified as a flammable liquid under normal handling.

Hygroscopicity

Strongly hygroscopic; absorbs moisture from air if left in open containers.

PPE Standard

Chemical-resistant gloves and safety glasses are the baseline for routine handling.

Ingestion Risk

Should never be used in food, drug or cosmetic applications; industrial grade only.

Spill Handling

Fully water-miscible; contain and absorb spills to prevent entry into drains and watercourses.

Signal word

Warning — GHS07 harmful and GHS08 health hazard pictograms apply.

This compound is harmful if swallowed and may cause organ damage, particularly to the kidneys, through prolonged or repeated exposure. It should never be substituted into food-, drug- or cosmetic-grade applications; this is an industrial grade material only. It should be handled with chemical-resistant gloves and eye protection, and spills should be contained promptly given its full miscibility with water. Full first-aid, storage, spill and PPE guidance is in the MSDS issued with every shipment, and should be read in full before this material is handled.

07 / STORAGE & SHELF LIFE

Keeping it on spec between delivery and use

General storage guidance for this grade. Site-specific storage rules, segregation requirements and re-test intervals should follow your own EHS procedures and the MSDS issued with your batch.

Storage TemperatureAmbient, indoor
ContainerSealed drums / IBC / bulk tank
Typical Shelf Life24 months, unopened
Keep Away FromStrong oxidizers, moisture ingress
Beyond Shelf LifeRe-assay before use

Store in tightly closed containers in a dry, ambient-temperature area, away from strong oxidising agents. Because the material is strongly hygroscopic, containers should be kept sealed between uses to avoid moisture pickup, which can affect downstream esterification stoichiometry. Re-check assay and water content on a batch held past its retest date before use.

08 / PACKING & EXPORT

How it ships from Indonesia

Standard packing and export terms for this product. Confirm exact figures against your order — they vary slightly by destination and quantity.

Standard Packing200 kg drums / 1,000 L IBC
Bulk PackingISO tank / bulk tanker on request
Min. OrderFrom 1 tonne
Lead Time2 – 3 weeks
Export TermsFOB · CFR · CIF
09 / QUALITY & DOCUMENTATION

What travels with every batch

Specification is agreed before the purchase order, not discovered on arrival. Every shipment of Diethylene Glycol leaves with a documented, checkable paper trail.

Doc 01

Certificate of Analysis

Batch-wise assay, colour and key physical constants, issued against the agreed specification so your QC team can check it, not just file it.

Doc 02

Safety Data Sheet

GHS-format SDS in English covering hazard classification, handling, storage, first-aid and spill response for the exact grade shipped.

Doc 03

Technical Data Sheet

Reference physical and chemical properties, recommended storage and typical applications, for internal circulation to your process or R&D teams.

Doc 04

Certificate of Origin

Confirms Indonesian origin for customs clearance and any preferential-duty claim at your destination port.

Doc 05

Dangerous Goods Declaration

UN packing group, classification and shipper's declaration prepared ahead of loading so documentation never holds up customs.

Doc 06

Third-Party Inspection

Independent pre-shipment inspection and re-sampling can be arranged on request, at your cost, for buyers who require it as a matter of policy.

10 / FAQ

Frequently asked questions

What buyers most often ask our sales desk about this grade.

01What is Diethylene Glycol used for?+
Predominantly as a flexibilising co-monomer glycol in unsaturated polyester resin manufacture; it is also used in certain polyurethane polyester-polyol systems, as a high-boiling industrial solvent, and as feedstock for triethylene glycol and morpholine production.
02What is the CAS number of Diethylene Glycol?+
Its CAS Registry Number is 111-46-6, with molecular formula C₄H₁₀O₃ and a molar mass of 106.12 g/mol.
03How is Diethylene Glycol made?+
As a co-product of the industrial hydration of ethylene oxide to monoethylene glycol: a portion of the ethylene oxide reacts further with the monoethylene glycol already formed, and the resulting glycol mixture is separated by vacuum distillation.
04What purity grade does Chelora Chemicals supply?+
We supply industrial grade (99.5%+ purity) as bulk liquid, suited to unsaturated polyester resin, polyurethane and industrial solvent applications. Each batch ships with a certificate of analysis.
05Is Diethylene Glycol hazardous?+
Yes, in the sense relevant to industrial handling. It is harmful if swallowed and may cause kidney damage through prolonged or repeated exposure, and it must never be used in food, drug or cosmetic applications. It should be handled with the PPE and precautions specified in the MSDS supplied with each shipment.
06Why do resin formulators blend diethylene glycol with other glycols rather than using it alone?+
Its central ether linkage makes the cured polyester network it contributes to more flexible than one built purely from monoethylene glycol, so formulators blend the two glycols in different ratios to dial in the exact balance of flexibility and hardness a given resin application calls for.
07What packing options are available?+
Standard packing is 200 kg drums or 1,000 litre IBCs, with ISO tank or bulk tanker shipment available for larger volumes.
08How long does delivery take?+
Typical lead time is two to three weeks plus transit, depending on whether the grade is ex-stock or made to order and your destination port. A firm date is confirmed in the written quotation.
09Can I get a sample before placing a bulk order?+
Yes. Pre-shipment samples and a batch certificate of analysis can be arranged so your QC team can verify the specification before committing to volume.
10Do you supply other glycols as well?+
Yes, we also supply Triethylene Glycol, Mono Propylene Glycol and Propylene Oxide, related products from the same alkylene oxide hydration chemistry family.
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