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Vinyl Nitrile Monomer · CAS 107-13-1

Acrylonitrile

CH2=CHCN Molar mass 53.06 g/mol

The vinyl nitrile monomer supplied by Chelora Chemicals — known in the trade as AN, the essential feedstock for acrylic fibre, ABS resin, nitrile rubber and adiponitrile manufacture — exported from Indonesia in inhibited, stabilised ISO tanks and drums with full batch documentation on every shipment.

Identification Sheet REP.
IUPAC nameProp-2-enenitrile
CAS number107-13-1
Molecular formulaCH₂=CHCN
Molar mass53.06 g/mol
AppearanceColourless to pale yellow liquid, pungent odour
Common synonymsAcrylonitrile, Vinyl Cyanide, Propenenitrile, AN
Melting Point−83 °Clit.
Boiling Point77 °Cat 1 atm
Specific Gravity0.81at 20 °C
Flash Point0 °Cclosed cup
AppearanceColourless to pale yellow liquidpungent, garlic/onion-like odour
Purity Offered99.5%+polymer grade, inhibited liquid
01 / PRODUCT DOSSIER

What Acrylonitrile is, and why buyers source it

A working overview of the compound's chemistry, its role as a reactive vinyl nitrile, and the grade Chelora Chemicals keeps in regular supply.

Acrylonitrile combines a reactive vinyl double bond with a nitrile group on the same three-carbon backbone. The vinyl group makes it an eager radical-polymerisation monomer much like styrene or acrylic acid, while the polar, strongly electron-withdrawing nitrile group gives polymers built from it distinctive chemical resistance, barrier properties and, after further reaction, a route into nitrogen-containing intermediates such as adiponitrile.

At room temperature it is a colourless to pale-yellow, highly flammable and toxic liquid with a sharp, pungent odour, partially soluble in water and miscible with most organic solvents. Like other reactive vinyl monomers it is shipped with a polymerisation inhibitor and requires temperature-controlled, oxygen-headspace-controlled storage to remain stable in transit.

Where it fits in the synthesis chain

Acrylonitrile's largest use is as the monomer for polyacrylonitrile (acrylic and modacrylic fibre) and as a comonomer in ABS and SAN engineering resins and acrylonitrile-butadiene (nitrile) rubber, prized for its oil and solvent resistance. A major further use is electrochemical or catalytic dimerisation to adiponitrile, which is hydrogenated to hexamethylenediamine, the essential nylon 66 co-monomer — tying acrylonitrile directly into the nylon supply chain.

Grade we supply

Chelora Chemicals offers Acrylonitrile in a single polymer grade (99.5%+ assay, inhibited with hydroquinone monomethyl ether or an equivalent stabiliser) suitable for fibre, resin, rubber and adiponitrile-precursor manufacture, supplied with a batch-wise certificate of analysis.

02 / MANUFACTURING ROUTE

How Acrylonitrile is made

An overview of the production route for orientation purposes. Our manufacturing partners' own process parameters and in-process controls are proprietary and are not disclosed beyond what is needed to interpret the certificate of analysis.

Acrylonitrile is manufactured almost exclusively by the Sohio process: the catalytic ammoxidation of propylene with ammonia and oxygen (air) over a mixed metal oxide catalyst, typically bismuth molybdate-based, in a fluidised-bed reactor at moderate temperature: CH₂=CHCH₃ + NH₃ + 1.5 O₂ → CH₂=CHCN + 3 H₂O. Acetonitrile and hydrogen cyanide form as recoverable co-products of the same reaction.

Why the Sohio ammoxidation process is universal

Ammoxidation converts propylene, ammonia and oxygen directly into acrylonitrile in a single catalytic step with good selectivity and well-understood fluidised-bed engineering, which is why it has been the dominant commercial route since the process was first commercialised and remains essentially the only route used at scale today.

03 / APPLICATIONS

Industries and processes that use it

Acrylonitrile is consumed across fibre, engineering resin, rubber and nylon-chain manufacture, where its combination of vinyl reactivity and nitrile chemistry is the main draw. The fields below account for most of the demand we see through our export desk.

Field 01

Polyacrylonitrile (Acrylic) Fibre

Polymerised to polyacrylonitrile, the basis of acrylic and modacrylic textile fibre, and a precursor to carbon fibre via controlled pyrolysis.

Field 02

ABS & SAN Engineering Resins

Copolymerised with styrene and butadiene to make ABS, and with styrene alone to make SAN, both widely used engineering thermoplastics.

Field 03

Nitrile (NBR) Rubber

Copolymerised with butadiene to make acrylonitrile-butadiene rubber, prized for its oil, fuel and solvent resistance in seals, hoses and gaskets.

Field 04

Adiponitrile & Nylon 66 Chain

Electrochemically or catalytically dimerised to adiponitrile, then hydrogenated to hexamethylenediamine, the essential nylon 66 co-monomer.

04 / REACTION CHEMISTRY

How the molecule is typically carried forward

The conjugated vinyl-nitrile system governs almost all of this molecule's further reaction chemistry. Reaction classes below account for most of the ways Acrylonitrile is converted into a finished product or intermediate.

Free-Radical Polymerisation

A radical initiator opens the vinyl double bond and propagates a growing polymer chain, the basis of polyacrylonitrile fibre and ABS/SAN resin manufacture.

Electrohydrodimerisation (to Adiponitrile)

Two acrylonitrile molecules couple reductively at an electrode to form adiponitrile, the direct precursor to hexamethylenediamine for nylon 66.

Free-Radical Copolymerisation (NBR)

Copolymerises with butadiene to build acrylonitrile-butadiene rubber, with acrylonitrile content tuned to balance oil resistance against low-temperature flexibility.

Catalytic Ammoxidation (Upstream)

Propylene, ammonia and oxygen combine over a fluidised-bed catalyst to form acrylonitrile itself, the first and essentially only industrial step in the whole chain.

05 / RELATED BUILDING BLOCKS

Acrylonitrile against other amines we supply

Buyers sourcing Acrylonitrile for fibre, resin, rubber or nylon-chain manufacture often need a related monomer or the downstream nylon diamine. A quick reference to what else is on our regular supply list.

ProductCAS NumberCategoryNotes
Acrylonitrile107-13-1Vinyl nitrile monomerThe product on this page — the feedstock for acrylic fibre, ABS, NBR and adiponitrile.
Acrylic Acid79-10-7Vinyl carboxylic acid monomerA related propylene-derived vinyl monomer — see its product page.
Hexamethylenediamine124-09-4Six-carbon diamineThe nylon 66 diamine made downstream via adiponitrile — see its product page.
Styrene Monomer100-42-5Vinyl aromatic monomerThe comonomer paired with acrylonitrile in ABS and SAN resin — see its product page.

Exact physical constants and purity specifications are confirmed per batch on the certificate of analysis — treat the notes above as a sourcing guide, not a specification sheet, for products other than Acrylonitrile.

06 / HAZARD & HANDLING

Safety classification at a glance

Based on GHS classification as commonly listed for this substance. This is a summary for orientation only — always work from the current safety data sheet supplied with your specific batch.

H225

Highly flammable liquid and vapour.

H331

Toxic if inhaled.

H315

Causes skin irritation.

H351

Suspected of causing cancer.

PPE Standard

Chemical-resistant gloves, splash goggles and supplied-air or cartridge respiratory protection are mandatory for routine handling.

Fire Precaution

Keep away from heat, sparks and open flame; ground and bond containers during transfer given the very low flash point.

Polymerisation Hazard

Can polymerise violently if the inhibitor is depleted or the material is exposed to excess heat or contamination — monitor inhibitor level in storage.

Signal word

Danger — GHS02 flammable, GHS06 toxic and GHS08 health-hazard pictograms apply.

This compound is a highly flammable liquid that is toxic if inhaled, causes skin irritation, and is suspected of causing cancer. It can also polymerise violently if its inhibitor is depleted. It must be handled only with chemical-resistant gloves, splash-proof eye protection, supplied-air or cartridge respiratory protection, and kept well away from heat and open flame. Full first-aid, storage, spill and PPE guidance is in the MSDS issued with every shipment, and must be read in full and followed without exception before this material is handled.

07 / STORAGE & SHELF LIFE

Keeping it on spec between delivery and use

General storage guidance for this grade. Site-specific storage rules, segregation requirements and re-test intervals should follow your own EHS procedures and the MSDS issued with your batch.

Storage TemperatureCool, below 20 °C, out of sunlight
ContainerSealed, inhibited drums / ISO tank
Typical Shelf Life3 – 6 months, inhibitor-dependent
Keep Away FromHeat, light, acids, bases, oxidizers
Beyond Shelf LifeRe-check inhibitor & purity before use

Store in a cool area below 20 °C, out of direct sunlight and away from heat sources, acids, bases and oxidizing agents, in tightly closed original packaging with the specified minimum oxygen headspace to keep the inhibitor effective. Only trained personnel using proper respiratory protection should handle this material given its acute toxicity. If a batch is held past its retest date, re-check inhibitor level, assay and colour before use.

08 / PACKING & EXPORT

How it ships from Indonesia

Standard packing and export terms for this product. Confirm exact figures against your order — they vary slightly by destination and quantity.

Standard Packing200 L drums, inhibited (liquid)
Bulk PackingISO tank on request
Min. OrderFrom 1 tonne
Lead Time2 – 3 weeks
Export TermsFOB · CFR · CIF
09 / QUALITY & DOCUMENTATION

What travels with every batch

Specification is agreed before the purchase order, not discovered on arrival. Every shipment of Acrylonitrile leaves with a documented, checkable paper trail.

Doc 01

Certificate of Analysis

Batch-wise assay (by titration/GC), colour and relevant physical constants, issued against the agreed specification so your QC team can check it, not just file it.

Doc 02

Safety Data Sheet

GHS-format SDS in English covering hazard classification, handling, storage, first-aid and spill response for the exact grade of Acrylonitrile shipped.

Doc 03

Technical Data Sheet

Reference physical and chemical properties, recommended storage and typical applications, for internal circulation to your process or R&D teams.

Doc 04

Certificate of Origin

Confirms Indonesian origin for customs clearance and any preferential-duty claim at your destination port.

Doc 05

Dangerous Goods Declaration

UN packing group, classification and shipper's declaration prepared ahead of loading so documentation never holds up customs.

Doc 06

Third-Party Inspection

Independent pre-shipment inspection and re-sampling can be arranged on request, at your cost, for buyers who require it as a matter of policy.

10 / FAQ

Frequently asked questions

What buyers most often ask our sales desk about this grade.

01What is Acrylonitrile used for?+
As the monomer for polyacrylonitrile (acrylic fibre and carbon-fibre precursor), a comonomer in ABS/SAN resins and nitrile (NBR) rubber, and as the feedstock for adiponitrile, which is hydrogenated to hexamethylenediamine for nylon 66.
02What is the CAS number of Acrylonitrile?+
Its CAS Registry Number is 107-13-1, with molecular formula CH₂=CHCN and a molar mass of 53.06 g/mol.
03How is Acrylonitrile made?+
By the Sohio process: catalytic ammoxidation of propylene with ammonia and oxygen over a bismuth molybdate-based catalyst in a fluidised-bed reactor.
04What grade does Chelora Chemicals supply?+
We supply a single polymer grade (99.5%+ assay, inhibited) suitable for fibre, resin, rubber and adiponitrile-precursor manufacture, supplied with a certificate of analysis.
05Is Acrylonitrile hazardous?+
Yes, significantly. It is a highly flammable liquid that is toxic if inhaled, causes skin irritation, and is suspected of causing cancer. It must be handled only by trained personnel using the PPE and precautions specified in the MSDS supplied with each shipment.
06How is Acrylonitrile connected to nylon 66 manufacture?+
Two molecules of acrylonitrile are reductively coupled at an electrode (electrohydrodimerisation) to form adiponitrile, which is then catalytically hydrogenated to hexamethylenediamine, the essential diamine co-monomer condensed with adipic acid to make nylon 66.
07What packing options are available?+
Standard packing is 200 L inhibited drums for the liquid, with ISO tank shipment available on request for bulk quantities.
08How long does delivery take?+
Typical lead time is two to three weeks plus transit, depending on whether the grade is ex-stock or made to order and your destination port. A firm date is confirmed in the written quotation.
09Can I get a sample before placing a bulk order?+
Given the handling precautions this material requires, sample logistics are arranged case by case — contact our desk to discuss what is practical for your facility.
10Do you supply Hexamethylenediamine as well?+
Yes, we also supply Hexamethylenediamine, the nylon 66 diamine made downstream of acrylonitrile via adiponitrile, along with Acrylic Acid and Styrene Monomer.
Request This Grade

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