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Tertiary Aliphatic Amine · CAS 121-44-8

Triethylamine

(CH3CH2)3N Molar mass 101.19 g/mol

The tertiary ethylamine supplied by Chelora Chemicals — a workhorse catalytic base and acid scavenger across organic synthesis, and a standard rubber-vulcanisation accelerator activator and polyurethane catalyst — exported from Indonesia with full batch documentation on every shipment.

Identification Sheet REP.
IUPAC nameN,N-Diethylethanamine
CAS number121-44-8
Molecular formula(CH₃CH₂)₃N
Molar mass101.19 g/mol
AppearanceColourless liquid
Common synonymsTriethylamine, N,N-Diethylethanamine, TEA
Melting Point–115 °Clit.
Boiling Point89 – 90 °Cat 1 atm
Specific Gravity0.725 – 0.728at 20 °C
Flash Point–7 °Cclosed cup
AppearanceColourless liquidstrong ammonia-like odour
Purity Offered99% / 99.5%+technical & high-purity
01 / PRODUCT DOSSIER

What Triethylamine is, and why buyers source it

A working overview of the compound's chemistry, its place as the tertiary member of the ethylamine family, and the grades Chelora Chemicals keeps in regular supply.

Triethylamine is a tertiary aliphatic amine: three ethyl groups attached to a nitrogen with no N–H bonds and a freely available lone pair. With no N–H to complicate matters, it behaves as a clean, non-nucleophilic-leaning base rather than a nucleophile in most reactions, which is exactly the property that makes it so widely used — it readily mops up the acid (typically HCl) generated in acylation, sulfonylation and alkylation reactions without itself becoming a competing reactant.

At room temperature it is a colourless, highly flammable, corrosive liquid with a strong ammonia-like odour, miscible with most organic solvents and moderately soluble in water. It is handled with the solvent-class and corrosive-liquid precautions typical of low-boiling amines.

Where it fits in the synthesis chain

Triethylamine's single largest role is as a catalytic base and acid scavenger in organic synthesis — most commonly in acylation and sulfonylation reactions, where it neutralises the HCl by-product as it forms. Beyond this, it is used as a rubber accelerator activator in vulcanisation chemistry, a catalyst for polyurethane foam and epoxy resin curing, an anti-livering agent for urea- and melamine-based enamels, a corrosion inhibitor and propellant component, a flux additive for copper soldering, and a reagent in quaternary ammonium compound manufacture.

Grades we supply

Chelora Chemicals offers Triethylamine in technical grade (≈99% assay) for standard rubber and formulation chemistry, and high-purity grade (99.5%+) for pharmaceutical and fine-chemical synthesis sensitive to colour and water content. Both grades are supplied with a batch-wise certificate of analysis.

02 / MANUFACTURING ROUTE

How Triethylamine is made

An overview of the production route for orientation purposes. Our manufacturing partners' own process parameters and in-process controls are proprietary and are not disclosed beyond what is needed to interpret the certificate of analysis.

Triethylamine is manufactured by the catalytic reaction of ethanol and ammonia in the presence of hydrogen over a copper-nickel-clay catalyst at around 165 – 190 °C, with ethylamine and diethylamine forming as co-products: 3 C₂H₅OH + NH₃ → (C₂H₅)₃N + 3 H₂O. The crude reaction mixture is absorbed in ethanol, then separated, dehydrated and fractionated to isolate the triethylamine fraction at the required assay. A related vapour-phase process reacting ammonia with ethanol is also used industrially.

Why the ethanol/ammonia route is preferred

Catalytic amination of ethanol is continuous, scalable and economically efficient because all three ethylamine co-products — mono-, di- and tri-ethylamine — have established commercial markets, so the process yields no wasted by-product stream.

03 / APPLICATIONS

Industries and processes that use it

Triethylamine is consumed broadly across pharmaceutical and fine-chemical synthesis as an acid scavenger, and by rubber, polyurethane and specialty formulation chemistry. The fields below account for most of the demand we see through our export desk.

Field 01

Catalytic Base & Acid Scavenger

Neutralises the HCl by-product generated in acylation and sulfonylation reactions, a routine role across pharmaceutical and fine-chemical synthesis.

Field 02

Rubber Accelerator Activator

Used as an activator in rubber vulcanisation accelerator systems, improving cure efficiency in tyre and technical rubber-goods manufacture.

Field 03

Polyurethane & Epoxy Catalyst

A catalyst for polyurethane foam formation and epoxy resin curing, and a curing/hardening agent for other polymer systems.

Field 04

Corrosion Inhibitor & Quaternary Ammonium Chemistry

Used as a corrosion inhibitor and propellant component, and as a reagent in quaternary ammonium compound manufacture.

04 / REACTION CHEMISTRY

How the molecule is typically carried forward

The tertiary amine's non-nucleophilic basicity governs almost all of this molecule's further reaction chemistry. Reaction classes below account for most of the ways Triethylamine is used in a finished synthesis step.

Acid Scavenging in Acylation

Neutralises the HCl generated as an acid chloride reacts with an alcohol or amine, driving the acylation reaction to completion without itself being consumed as a reactant.

Acid Scavenging in Sulfonylation

Performs the same scavenging role in sulfonyl chloride chemistry, a routine step in protecting-group and activation chemistry.

Base Catalysis in Polyurethane Formation

Catalyses the reaction between isocyanates and polyols in polyurethane foam manufacture, accelerating gel and blow reactions.

Quaternisation

Reacts with alkylating agents to give quaternary ammonium salts used in corrosion-inhibitor and specialty surfactant chemistry.

05 / RELATED BUILDING BLOCKS

Triethylamine against its mono- and di-ethyl relatives we supply

Buyers sourcing triethylamine often need its primary or secondary relative for a parallel step. A quick reference to what else is on our regular supply list.

ProductCAS NumberCategoryNotes
Triethylamine121-44-8Tertiary ethylamineThe product on this page — the trialkylated ethylamine in our range.
Ethylamine75-04-7Primary ethylamineThe monoalkylated relative, co-produced from the same feedstock — see its product page.
Diethylamine109-89-7Secondary ethylamineThe dialkylated relative, co-produced from the same feedstock — see its product page.
Trimethylamine75-50-3Tertiary methylamineA related tertiary amine elsewhere in our range — see its product page.

Exact physical constants and purity specifications are confirmed per batch on the certificate of analysis — treat the notes above as a sourcing guide, not a specification sheet, for products other than Triethylamine.

06 / HAZARD & HANDLING

Safety classification at a glance

Based on GHS classification as commonly listed for this substance. This is a summary for orientation only — always work from the current safety data sheet supplied with your specific batch.

H225

Highly flammable liquid and vapour.

H302

Harmful if swallowed.

H311

Toxic in contact with skin.

H314

Causes severe skin burns and eye damage.

H331

Toxic if inhaled.

PPE Standard

Impervious gloves, chemical splash goggles or a face shield, and suitable respiratory protection are the baseline for routine handling.

Ignition Sources

Highly flammable; keep away from open flames, sparks, static discharge and other ignition sources, and bond/ground containers during transfer.

Signal word

Danger — GHS02 flammable, GHS05 corrosive and GHS06 toxic pictograms apply.

This compound is a highly flammable, corrosive liquid that is toxic in contact with skin or if inhaled, causes severe skin burns and eye damage, and is harmful if swallowed. It must be handled with impervious gloves, splash-proof eye protection and suitable respiratory protection in a well-ventilated area, kept away from all ignition sources. Full first-aid, storage, spill and PPE guidance is in the MSDS issued with every shipment, and should be read in full before this material is handled.

07 / STORAGE & SHELF LIFE

Keeping it on spec between delivery and use

General storage guidance for this grade. Site-specific storage rules, segregation requirements and re-test intervals should follow your own EHS procedures and the MSDS issued with your batch.

Storage TemperatureCool, ambient
ContainerSealed drums / ISO tank
Typical Shelf Life24 months, unopened
Keep Away FromOpen flames, oxidizers, strong acids
Beyond Shelf LifeRe-assay before use

Store in a cool, dry, well-ventilated area away from direct sunlight, open flames and other ignition sources, in tightly closed original packaging, segregated from strong oxidizing agents and strong acids. If a batch is held past its retest date, re-check assay, colour and water content before use.

08 / PACKING & EXPORT

How it ships from Indonesia

Standard packing and export terms for this product. Confirm exact figures against your order — they vary slightly by destination and quantity.

Standard Packing200 kg drums
Bulk PackingIBC / ISO tank
Min. OrderFrom 1 drum
Lead Time2 – 3 weeks
Export TermsFOB · CFR · CIF
09 / QUALITY & DOCUMENTATION

What travels with every batch

Specification is agreed before the purchase order, not discovered on arrival. Every shipment of Triethylamine leaves with a documented, checkable paper trail.

Doc 01

Certificate of Analysis

Batch-wise assay (by GC), colour and water content, issued against the agreed specification so your QC team can check it, not just file it.

Doc 02

Safety Data Sheet

GHS-format SDS in English covering hazard classification, handling, storage, first-aid and spill response for the exact grade shipped.

Doc 03

Technical Data Sheet

Reference physical and chemical properties, recommended storage and typical applications, for internal circulation to your process or R&D teams.

Doc 04

Certificate of Origin

Confirms Indonesian origin for customs clearance and any preferential-duty claim at your destination port.

Doc 05

Dangerous Goods Declaration

UN packing group, classification and shipper's declaration prepared ahead of loading so documentation never holds up customs.

Doc 06

Third-Party Inspection

Independent pre-shipment inspection and re-sampling can be arranged on request, at your cost, for buyers who require it as a matter of policy.

10 / FAQ

Frequently asked questions

What buyers most often ask our sales desk about this grade.

01What is Triethylamine used for?+
Mainly as a catalytic base and acid scavenger in acylation and sulfonylation chemistry; it is also used as a rubber accelerator activator, a polyurethane and epoxy catalyst, a corrosion inhibitor, and a reagent in quaternary ammonium compound manufacture.
02What is the CAS number of Triethylamine?+
Its CAS Registry Number is 121-44-8, with molecular formula (CH₃CH₂)₃N and a molar mass of 101.19 g/mol.
03How is Triethylamine made?+
By the catalytic reaction of ethanol and ammonia with hydrogen over a copper-nickel-clay catalyst, co-producing ethylamine and diethylamine, separated by fractionation.
04What purity grades does Chelora Chemicals supply?+
We supply technical grade (around 99% assay) for standard rubber and formulation chemistry, and high-purity grade (99.5%+) for pharmaceutical and fine-chemical synthesis. Each batch ships with a certificate of analysis.
05Is Triethylamine hazardous?+
Yes. It is a highly flammable, corrosive liquid that is toxic in contact with skin or if inhaled, and causes severe skin burns and eye damage. It must be handled with the PPE and precautions specified in the MSDS supplied with each shipment.
06Why is Triethylamine preferred over a primary amine as an acid scavenger?+
Because it has no N–H bonds, it cannot itself be acylated or sulfonylated as a competing reaction, so it cleanly mops up the acid by-product without interfering with the intended reaction.
07What packing options are available?+
Standard packing is 200 kg drums, with IBC or ISO tank shipment available for bulk orders.
08How long does delivery take?+
Typical lead time is two to three weeks plus transit, depending on whether the grade is ex-stock or made to order and your destination port. A firm date is confirmed in the written quotation.
09Can I get a sample before placing a bulk order?+
Yes. Pre-shipment samples and a batch certificate of analysis can be arranged so your QC team can verify the specification before committing to volume.
10Do you supply ethylamine and diethylamine as well?+
Yes, we also supply Ethylamine and Diethylamine, both co-produced from the same ethanol/ammonia feedstock.
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