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Carbon-Rich Refinery Residue · CAS 64741-79-3

Petroleum Coke

Predominantly carbon (C) Molar mass N/A (solid carbon residue)

The carbon-rich solid residue of delayed coking supplied by Chelora Chemicals — fuel-grade green coke for kilns and power generation, and calcined anode-grade coke for aluminium smelting and graphite electrodes — exported from Indonesia in bulk with full batch documentation on every shipment.

Identification Sheet REP.
Product typeCarbon-rich solid residue from delayed coking of vacuum residue (not a single compound)
CAS number64741-79-3
Principal composition>90% carbon, with sulphur, volatile matter and trace metals (V, Ni)
GradesGreen (fuel grade) and Calcined (anode grade)
AppearanceBlack solid, granular/lump (green) or fine, dense particles (calcined)
Common synonymsPetroleum Coke, Petcoke, Green Petroleum Coke (GPC), Calcined Petroleum Coke (CPC)
Fixed Carbon85 – 92% (green) · >98% (calcined)wt%
Sulphur Content0.5 – 6%grade/source dependent
Volatile Matter8 – 14% (green) · <0.5% (calcined)wt%
Real Density1.3 – 1.6 g/cm³ (green)2.0 – 2.1 g/cm³ (calcined)
AppearanceBlack solidlump/granular (green) or fine/dense (calcined)
Grades OfferedGreen (fuel grade) & Calcined (anode grade)low- and high-sulphur options
01 / PRODUCT DOSSIER

What Petroleum Coke is, and why buyers source it

A working overview of the product's composition, how fuel-grade and anode-grade material differ, and the grades Chelora Chemicals keeps in regular supply.

Petroleum Coke is a solid, carbon-rich residue left behind when the heaviest fraction of crude oil — vacuum residue, the material with too high a boiling point to distil off even under vacuum — is thermally cracked under controlled conditions. What remains is overwhelmingly elemental carbon, carrying with it whatever sulphur, nitrogen and trace metals (chiefly vanadium and nickel) were concentrated in the original heavy residue, since there is no further distillation step to remove them.

In its freshly produced ('green') form it is a black, solid, granular to lump material with a still-significant volatile-matter content. Calcining it at very high temperature drives off that remaining volatile matter and moisture, raising both its carbon purity and its electrical conductivity, and transforms it from a fuel-grade material into the anode-grade feedstock the aluminium and graphite-electrode industries specifically need.

Where each grade fits in the value chain

Green (uncalcined) petroleum coke, particularly higher-sulphur material, is used primarily as a fuel, substituting for coal in cement kiln firing and power generation, where its high fixed-carbon content and low ash give it a favourable calorific value despite its sulphur content needing to be managed through the plant's emissions-control system. Calcined petroleum coke (CPC), produced by calcining low-sulphur green coke at very high temperature, is the dominant raw material for carbon anodes used in aluminium smelting by the Hall-Héroult process, and is also used to manufacture graphite electrodes for electric-arc-furnace steelmaking and as a carbon-based reducing agent in processes such as titanium dioxide manufacture.

Grades we supply

Chelora Chemicals offers Petroleum Coke in green, fuel grade (for kiln and power-generation fuel use) and, on request, calcined, anode grade (for aluminium and graphite-electrode applications), each specified by sulphur content and the relevant carbon-purity parameters. Each grade is supplied with a batch-wise certificate of analysis.

02 / MANUFACTURING ROUTE

How Petroleum Coke is produced

An overview of the production route for orientation purposes. Our manufacturing partners' own process parameters and in-process controls are proprietary and are not disclosed beyond what is needed to interpret the certificate of analysis.

Petroleum Coke is produced by the delayed coking process: vacuum residue, the heaviest fraction left after an atmospheric and vacuum distillation of crude oil, is heated and fed into a large coke drum, where it is held at high temperature (roughly 480–515°C) under pressure for an extended period. Over this time, the heavy hydrocarbon molecules thermally crack: lighter products (coker gas, naphtha and gas oil fractions) are driven off and recovered as valuable refinery intermediates, while the carbon-rich material that cannot crack further accumulates and solidifies in the drum as green petroleum coke, which is then cut out hydraulically once the drum is full.

Where anode-grade material is wanted, green coke — selected for a sufficiently low starting sulphur and metals content — is calcined in a rotary kiln at 1,200–1,350°C. This calcining step drives off essentially all remaining moisture and volatile matter, increases the material's real density and electrical conductivity, and converts the green coke's porous structure into the denser, more ordered carbon structure that anode and graphite-electrode manufacture requires.

03 / APPLICATIONS

Industries and processes that use it

Petroleum Coke is consumed as both a high-carbon fuel and, once calcined, as the dominant carbon raw material for aluminium and graphite-electrode manufacture. The fields below account for most of the demand we see through our export desk.

Field 01

Cement Kiln & Power Plant Fuel

Green, higher-sulphur coke substitutes for coal as a high-carbon, high-calorific-value fuel in cement kiln firing and power generation.

Field 02

Aluminium Smelting Anodes

Calcined, low-sulphur coke is the dominant raw material for carbon anodes consumed in the Hall-Héroult aluminium smelting process.

Field 03

Graphite Electrode Manufacture

Calcined coke, further graphitised at very high temperature, is a key raw material for graphite electrodes used in electric-arc-furnace steelmaking.

Field 04

Metallurgical & Chemical Reducing Agent

Used as a carbon-based reducing agent in select metallurgical processes and in titanium dioxide manufacture.

04 / REACTION CHEMISTRY

How the product is typically carried forward

The material's high fixed-carbon content and its sulphur/metals profile govern almost all of its further industrial use. The categories below account for most of the ways Petroleum Coke is put to work.

Combustion (Fuel Use)

Green coke is pulverised and combusted in cement kilns or power-plant boilers, releasing its high carbon content as heat energy, with sulphur oxides managed through the plant's flue-gas desulphurisation system.

Calcination

Green coke is heated in a rotary kiln to drive off volatile matter and moisture, converting it to the denser, higher-purity calcined coke anode-grade manufacture requires.

Anode Baking

Calcined coke is blended with pitch binder and baked into solid carbon anode blocks, which are consumed in the aluminium electrolysis cell.

Graphitisation

Calcined coke, formed into electrode shapes with pitch binder, is heated to extremely high temperature (above 2,500 °C) to convert its carbon structure into graphite for electrode use.

05 / RELATED BUILDING BLOCKS

Petroleum Coke against other refinery products we supply

Buyers sourcing petroleum coke often also need other heavy-refinery or specialty petroleum products from the same crude barrel. A quick reference to what else is on our regular supply list.

ProductCAS NumberCategoryNotes
Petroleum Coke64741-79-3Carbon-rich refinery residueThe product on this page — green fuel-grade and calcined anode-grade coke.
Base Oil (Group I/II/III)Varies by groupLubricant base stockA related refinery product, from the lube-distillate end of the crude barrel — see its product page.
Paraffin Wax8002-74-2Paraffinic waxA related refinery-derived specialty product — see its product page.
Linear Alkyl Benzene67774-74-7Alkylaromatic surfactant feedstockA related specialty petrochemical product on our range — see its product page.

Exact composition, sulphur content and grade-specific specifications are confirmed per batch on the certificate of analysis — treat the notes above as a sourcing guide, not a specification sheet, for products other than Petroleum Coke.

06 / HAZARD & HANDLING

Safety classification at a glance

Based on GHS classification as commonly listed for this substance. This is a summary for orientation only — always work from the current safety data sheet supplied with your specific batch.

H335

May cause respiratory irritation (dust).

Combustible Dust

Can form a combustible dust cloud; dust-explosion precautions apply in bulk handling and conveying.

Self-Heating Potential

Bulk stockpiles can be subject to self-heating over time; stockpile management practices are used to monitor and mitigate this.

Low Acute Toxicity

Comparatively low acute oral and dermal toxicity; main hazard relates to dust inhalation and bulk-handling considerations.

PPE Standard

Dust-suitable respiratory protection and safety glasses are the baseline for routine bulk handling.

Dust Control

Minimise airborne dust during loading, unloading and conveying, particularly for fine calcined-grade material.

Signal word

Warning — GHS07 harmful pictogram applies for dust inhalation risk.

This product may cause respiratory irritation when handled as dust, and bulk stockpiles can be subject to self-heating and combustible-dust risk, both of which are managed through standard bulk-material stockpile and dust-control practices. It has a comparatively low acute toxicity profile otherwise. Routine bulk handling calls for dust-suitable respiratory protection and eye protection. Full first-aid, storage, spill and PPE guidance is in the MSDS issued with every shipment, and should be read in full before this material is handled.

07 / STORAGE & SHELF LIFE

Keeping it on spec between delivery and use

General storage guidance for this grade. Site-specific storage rules, segregation requirements and re-test intervals should follow your own EHS procedures and the MSDS issued with your batch.

Storage ConditionOpen or covered stockpile, bulk
ContainerBulk stockpile / bulk bags (small lots)
Typical Shelf LifeNo fixed shelf life for bulk solid
Keep Away FromIgnition sources, prolonged wetting/drying cycles
Stockpile ManagementMonitor for self-heating per standard bulk-carbon practice

Store as a bulk stockpile, following standard bulk-carbon stockpile management practices, including periodic temperature monitoring to detect self-heating and dust-suppression measures (such as water spray) during handling and in windy conditions. Keep away from ignition sources given the combustible-dust risk. Calcined, anode-grade material is typically handled and stored under tighter contamination-control measures than fuel-grade green coke, given its sensitivity to trace-element pickup.

08 / PACKING & EXPORT

How it ships from Indonesia

Standard packing and export terms for this product. Confirm exact figures against your order — they vary slightly by destination and quantity.

Standard PackingBulk vessel / bulk bags (small lots)
Bulk PackingBulk carrier / bulk truck
Min. OrderFrom 1,000 tonnes (bulk vessel); smaller lots on request
Lead Time3 – 5 weeks
Export TermsFOB · CFR · CIF
09 / QUALITY & DOCUMENTATION

What travels with every batch

Specification is agreed before the purchase order, not discovered on arrival. Every shipment of Petroleum Coke leaves with a documented, checkable paper trail.

Doc 01

Certificate of Analysis

Batch-wise assay, colour and key physical constants, issued against the agreed specification so your QC team can check it, not just file it.

Doc 02

Safety Data Sheet

GHS-format SDS in English covering hazard classification, handling, storage, first-aid and spill response for the exact grade shipped.

Doc 03

Technical Data Sheet

Reference physical and chemical properties, recommended storage and typical applications, for internal circulation to your process or R&D teams.

Doc 04

Certificate of Origin

Confirms Indonesian origin for customs clearance and any preferential-duty claim at your destination port.

Doc 05

Dangerous Goods Declaration

UN packing group, classification and shipper's declaration prepared ahead of loading so documentation never holds up customs.

Doc 06

Third-Party Inspection

Independent pre-shipment inspection and re-sampling can be arranged on request, at your cost, for buyers who require it as a matter of policy.

10 / FAQ

Frequently asked questions

What buyers most often ask our sales desk about this grade.

01What is Petroleum Coke used for?+
Green, higher-sulphur coke is used primarily as a fuel in cement kilns and power generation; calcined, low-sulphur coke is the dominant raw material for aluminium smelting anodes and graphite electrode manufacture, and is also used as a carbon reducing agent in select metallurgical and chemical processes.
02What is the CAS number of Petroleum Coke?+
Its CAS Registry Number is 64741-79-3. As a complex solid residue rather than a single compound, it has no defined molecular formula or molar mass; it is predominantly elemental carbon with sulphur, volatile matter and trace metals.
03How is Petroleum Coke produced?+
By delayed coking: vacuum residue from crude oil distillation is thermally cracked in a coke drum, with lighter products recovered and the carbon-rich solid residue left behind as green coke; anode-grade material is further calcined in a rotary kiln at 1,200–1,350 °C.
04What grades does Chelora Chemicals supply?+
We supply green, fuel grade as standard, with calcined, anode grade available on request, each specified by sulphur content and the relevant quality parameters for the intended end use. Each grade ships with a certificate of analysis.
05Is Petroleum Coke hazardous?+
It has a comparatively low acute toxicity profile but may cause respiratory irritation as dust, and bulk stockpiles are subject to self-heating and combustible-dust considerations managed through standard bulk-material practices. It should be handled with the PPE and precautions specified in the MSDS supplied with each shipment.
06Why does sulphur content matter so much in choosing between fuel-grade and anode-grade coke?+
Petroleum coke concentrates whatever sulphur was present in the original vacuum residue feedstock, with no purification step afterward to remove it; fuel-grade combustion in a kiln or power plant equipped with sulphur-emissions controls can tolerate relatively high sulphur coke, but anode-grade material destined for aluminium smelting needs a much lower sulphur content to meet smelting performance and environmental requirements, which is why green coke is specifically selected, and priced, by sulphur level before it is ever calcined.
07What packing and shipping options are available?+
Petroleum coke is typically shipped in bulk by vessel or bulk truck; bulk bags are available for smaller sample or trial lots on request.
08How long does delivery take?+
Typical lead time is three to five weeks plus transit for bulk vessel shipments, depending on grade availability and your destination port. A firm date is confirmed in the written quotation.
09Can I get a sample before placing a bulk order?+
Yes. Pre-shipment samples and a batch certificate of analysis can be arranged so your QC team can verify the specification before committing to volume.
10Do you supply other refinery-derived products as well?+
Yes, we also supply Base Oil and Paraffin Wax, related refinery-derived products.
Request This Grade

Need Petroleum Coke on spec, on time?

Send us your required grade (green/calcined), sulphur specification, quantity, packing preference and destination port. Our desk quotes most enquiries within one working day.