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Unsaturated Dicarboxylic Anhydride · CAS 108-31-6

Maleic Anhydride

C4H2O3 Molar mass 98.06 g/mol

The unsaturated dicarboxylic anhydride supplied by Chelora Chemicals — the essential feedstock for unsaturated polyester resin, alkyd coating and lubricant-additive manufacture — exported from Indonesia as molten liquid or briquetted flake with full batch documentation on every shipment.

Identification Sheet REP.
IUPAC nameFuran-2,5-dione
CAS number108-31-6
Molecular formulaC₄H₂O₃
Molar mass98.06 g/mol
AppearanceWhite crystalline solid or flake, acrid odour
Common synonymsMaleic Anhydride, MA, cis-Butenedioic Anhydride, Toxilic Anhydride
Melting Point53 °Clit.
Boiling Point202 °Cat 1 atm
Specific Gravity1.48solid, 20 °C
Flash Point102 °Cclosed cup
AppearanceWhite crystalline solid / flakesharp, acrid odour
Purity Offered99.5%+briquette / molten liquid grade
01 / PRODUCT DOSSIER

What Maleic Anhydride is, and why buyers source it

A working overview of the compound's chemistry, its role as a reactive unsaturated anhydride, and the grades Chelora Chemicals keeps in regular supply.

Maleic anhydride is the cyclic anhydride of cis-butenedioic acid, combining a reactive carbon-carbon double bond with two carbonyl groups held in a five-membered ring. That combination makes it both a good Diels-Alder dienophile and an efficient acylating agent, reacting readily with alcohols, amines and dienes — the chemistry behind its two largest industrial uses.

At room temperature it is a white crystalline solid or flake with a sharp, acrid odour, readily hydrolysed by moisture to maleic acid and soluble in most polar organic solvents. It is commonly shipped and handled as a molten liquid above its 53 °C melting point to simplify large-scale handling, and requires dry, moisture-free storage and transport since it reacts with water on contact.

Where it fits in the synthesis chain

Maleic anhydride's largest use is as a comonomer, condensed with glycols and unsaturated diacids, in unsaturated polyester resins (UPR) used for fibreglass-reinforced plastics, gelcoats and marine/construction composites. It is also esterified into plasticisers and lubricant-performance additives, reacted with dienes in Diels-Alder chemistry to make specialty resins, and copolymerised into maleated polymers used as compatibilisers and dispersants.

Grade we supply

Chelora Chemicals offers Maleic Anhydride in briquette/flake and molten-liquid form (99.5%+ assay) suitable for unsaturated polyester resin, alkyd coating and lubricant-additive manufacture, supplied with a batch-wise certificate of analysis.

02 / MANUFACTURING ROUTE

How Maleic Anhydride is made

An overview of the production route for orientation purposes. Our manufacturing partners' own process parameters and in-process controls are proprietary and are not disclosed beyond what is needed to interpret the certificate of analysis.

Maleic anhydride is manufactured almost exclusively by the catalytic gas-phase oxidation of n-butane (or, in older plants, benzene) with air over a vanadium-phosphorus-oxide catalyst in a fixed- or fluidised-bed reactor: C₄H₁₀ + 3.5 O₂ → C₄H₂O₃ + 4 H₂O. The crude anhydride vapour is then recovered, purified and either cast into briquettes/flake or kept molten for bulk shipment.

Why n-butane oxidation is the standard process

n-Butane oxidation converts a cheap, widely available light hydrocarbon directly into maleic anhydride in a single catalytic step with good selectivity, which is why it has displaced the older benzene-oxidation route and is now the dominant commercial process used worldwide.

03 / APPLICATIONS

Industries and processes that use it

Maleic Anhydride is consumed across composites, coatings, lubricant-additive and specialty-resin manufacture, where its combination of ring reactivity and unsaturation is the main draw. The fields below account for most of the demand we see through our export desk.

Field 01

Unsaturated Polyester Resins (UPR)

Condensed with glycols and other diacids to make unsaturated polyester resins used in fibreglass-reinforced plastics, gelcoats and marine/construction composites.

Field 02

Lubricant & Fuel Additives

Reacted with dienes and further derivatised into succinimide-type dispersant and detergent additives used in lubricant and fuel formulation.

Field 03

Alkyd & Coating Resins

Used alongside phthalic anhydride in alkyd resin cooking, improving drying speed, hardness and chemical resistance of paint and coating formulations.

Field 04

Maleated Polymers & Compatibilisers

Grafted onto polyolefins and other polymers to make maleated compatibilisers and dispersants used in polymer blending and composite manufacture.

04 / REACTION CHEMISTRY

How the molecule is typically carried forward

The ring strain, carbonyl reactivity and carbon-carbon double bond together govern almost all of this molecule's further reaction chemistry. Reaction classes below account for most of the ways Maleic Anhydride is converted into a finished product or intermediate.

Polyesterification

The anhydride ring opens and condenses with glycols and other diacids, releasing water and building the unsaturated polyester backbone used in UPR manufacture.

Diels-Alder Cycloaddition

Acts as an efficient dienophile, reacting with dienes such as butadiene to build specialty resins and the backbone for certain lubricant and fuel additives.

Free-Radical Grafting (Maleation)

Grafted onto polyolefin backbones under radical conditions to introduce polar anhydride functionality, the basis of maleated compatibiliser and dispersant chemistry.

Catalytic Gas-Phase Oxidation (Upstream)

n-Butane and air react over a vanadium-phosphorus-oxide catalyst to form maleic anhydride itself, the dominant industrial route in the whole chain.

05 / RELATED BUILDING BLOCKS

Maleic Anhydride against other amines we supply

Buyers sourcing Maleic Anhydride for composites, coatings or lubricant-additive manufacture often need a related anhydride or acid-chemistry intermediate. A quick reference to what else is on our regular supply list.

ProductCAS NumberCategoryNotes
Maleic Anhydride108-31-6Unsaturated dicarboxylic anhydrideThe product on this page — the feedstock for UPR, alkyd resins and lubricant additives.
Phthalic Anhydride85-44-9Aromatic dicarboxylic anhydrideThe related aromatic anhydride used alongside maleic anhydride in alkyd and UPR resins — see its product page.
Acrylic Acid79-10-7Vinyl carboxylic acid monomerAnother reactive unsaturated acid-chemistry monomer — see its product page.
Mono Ethylene Glycol107-21-1Diol / polyester comonomerA common glycol comonomer condensed with maleic anhydride in UPR manufacture — see its product page.

Exact physical constants and purity specifications are confirmed per batch on the certificate of analysis — treat the notes above as a sourcing guide, not a specification sheet, for products other than Maleic Anhydride.

06 / HAZARD & HANDLING

Safety classification at a glance

Based on GHS classification as commonly listed for this substance. This is a summary for orientation only — always work from the current safety data sheet supplied with your specific batch.

H302

Harmful if swallowed.

H315

Causes skin irritation.

H318

Causes serious eye damage.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

PPE Standard

Chemical-resistant gloves, splash goggles and respiratory protection against dust/fume are mandatory for routine handling.

Moisture Precaution

Keep strictly dry; contact with water or moisture generates maleic acid and heat.

Sensitisation Precaution

Repeated exposure can cause respiratory sensitisation; good ventilation and dust/fume control are essential.

Signal word

Danger — GHS05 corrosive, GHS07 irritant and GHS08 respiratory-sensitiser pictograms apply.

This compound is harmful if swallowed, causes skin irritation and serious eye damage, and may cause allergy or asthma symptoms or breathing difficulties if inhaled, including through sensitisation on repeated exposure. It must be handled only with chemical-resistant gloves, splash-proof eye protection, and respiratory protection against dust or fume, and kept strictly dry. Full first-aid, storage, spill and PPE guidance is in the MSDS issued with every shipment, and must be read in full and followed without exception before this material is handled.

07 / STORAGE & SHELF LIFE

Keeping it on spec between delivery and use

General storage guidance for this grade. Site-specific storage rules, segregation requirements and re-test intervals should follow your own EHS procedures and the MSDS issued with your batch.

Storage ConditionDry, sealed; molten grade kept above 53 °C
ContainerMoisture-barrier bags / drums / heated tank
Typical Shelf Life12 months, solid grade, sealed
Keep Away FromMoisture, strong bases, oxidizers
Beyond Shelf LifeRe-check assay & free acid before use

Store in a dry, sealed area away from moisture, strong bases and oxidizing agents. The molten-liquid grade must be kept in a heated, insulated tank above its 53 °C melting point with dry nitrogen blanketing to prevent hydrolysis and oxidation. Only trained personnel using proper PPE and dust/fume control should handle this material. If a batch is held past its retest date, re-check assay and free maleic acid content before use.

08 / PACKING & EXPORT

How it ships from Indonesia

Standard packing and export terms for this product. Confirm exact figures against your order — they vary slightly by destination and quantity.

Standard Packing (Solid)25 kg moisture-barrier bags, briquette/flake
Bulk Packing (Liquid)Heated ISO tank / tank truck, molten
Min. OrderFrom 1 tonne
Lead Time2 – 3 weeks
Export TermsFOB · CFR · CIF
09 / QUALITY & DOCUMENTATION

What travels with every batch

Specification is agreed before the purchase order, not discovered on arrival. Every shipment of Maleic Anhydride leaves with a documented, checkable paper trail.

Doc 01

Certificate of Analysis

Batch-wise assay (by titration/GC), colour and relevant physical constants, issued against the agreed specification so your QC team can check it, not just file it.

Doc 02

Safety Data Sheet

GHS-format SDS in English covering hazard classification, handling, storage, first-aid and spill response for the exact grade of Maleic Anhydride shipped.

Doc 03

Technical Data Sheet

Reference physical and chemical properties, recommended storage and typical applications, for internal circulation to your process or R&D teams.

Doc 04

Certificate of Origin

Confirms Indonesian origin for customs clearance and any preferential-duty claim at your destination port.

Doc 05

Dangerous Goods Declaration

UN packing group, classification and shipper's declaration prepared ahead of loading so documentation never holds up customs.

Doc 06

Third-Party Inspection

Independent pre-shipment inspection and re-sampling can be arranged on request, at your cost, for buyers who require it as a matter of policy.

10 / FAQ

Frequently asked questions

What buyers most often ask our sales desk about this grade.

01What is Maleic Anhydride used for?+
As the key comonomer in unsaturated polyester resins (UPR) for fibreglass composites and gelcoats, in alkyd coating resins, in lubricant and fuel dispersant additives, and in maleated polymer compatibilisers.
02What is the CAS number of Maleic Anhydride?+
Its CAS Registry Number is 108-31-6, with molecular formula C₄H₂O₃ and a molar mass of 98.06 g/mol.
03How is Maleic Anhydride made?+
By the catalytic gas-phase oxidation of n-butane with air over a vanadium-phosphorus-oxide catalyst, which has largely replaced the older benzene-oxidation route.
04What grades does Chelora Chemicals supply?+
We supply briquette/flake and molten-liquid grades (99.5%+ assay) suitable for UPR, alkyd coating and lubricant-additive manufacture, supplied with a certificate of analysis.
05Why is Maleic Anhydride shipped molten?+
Above its 53 °C melting point it is a free-flowing liquid that can be pumped and metered directly into resin-cooking equipment, which simplifies large-scale handling compared with solid flake.
06Is Maleic Anhydride hazardous?+
Yes. It is harmful if swallowed, causes skin irritation and serious eye damage, and may cause allergy, asthma symptoms or breathing difficulties if inhaled, including respiratory sensitisation on repeated exposure, so it must be handled with the PPE specified in the MSDS supplied with each shipment.
07What packing options are available?+
Standard packing is 25 kg moisture-barrier bags for briquette/flake grade, with heated ISO tank or tank-truck shipment available for molten bulk quantities.
08How long does delivery take?+
Typical lead time is two to three weeks plus transit, depending on grade and quantity. A firm date is confirmed in the written quotation.
09Can I get a sample before placing a bulk order?+
Yes, small sample quantities of Maleic Anhydride can generally be arranged for qualification testing — contact our desk with your application for a sample quote.
10Do you supply Phthalic Anhydride as well?+
Yes, we also supply Phthalic Anhydride, the related aromatic dicarboxylic anhydride commonly used alongside maleic anhydride in alkyd and polyester resin formulations.
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